Truxene

Base Information

• Chemical Name: Truxene
• CAS No.: 548-35-6
• Molecular Formula: C27H18
• Molecular Weight: 342.44
• Hs Code.: 2919100000
• European Community (EC) Number: 208-944-7
• NSC Number: 5559
• DSSTox Substance ID: DTXSID60203277
• Nikkaji Number: J342.529K
• Wikipedia: Truxene
• Wikidata: Q15910408
• Mol file: 548-35-6.mol

Synonyms:Truxene;548-35-6;10,15-Dihydro-5H-diindeno[1,2-a:1',2'-c]fluorene;Truxen;.alpha.-Truxene;5H-Tribenzo[a,f,k]trindene, 10,15-dihydro-;Benzene, tribenzylene-;10,15-Dihydro-5H-tribenzo(a,f,k)triindene;EINECS 208-944-7;10,15-dihydro-5H-tribenzo[a,f,k]triindene;heptacyclo[18.7.0.02,10.03,8.011,19.012,17.021,26]heptacosa-1,3,5,7,10,12,14,16,19,21,23,25-dodecaene;Tribenzylenebenzene;5H-Tribenzo(a,f,k)trindene, 10,15-dihydro-;C27H18;Truxene, >/=98%;DTXSID60203277;NSC5559;EX-A1406;NSC 5559;NSC-5559;MFCD00021180;AKOS024332973;C27-H18;CS-W011897;AS-55966;10,15-Dihydro-5H-tribenzo[a,f,k]trindene;T2752;C15972;5H-Diindeno[1,2'-c]fluorene, 10,15-dihydro-;10,15-Dihydro-5H-diindeno[1,2-a:1,2-c]fluorene;5H-Diindeno(1,2-a:1',2'-c)fluorene, 10,15-dihydro-

Chemical Property of Truxene

Chemical Property:

• Vapor Pressure: 9.97E-13mmHg at 25°C
• Melting Point: 370°C(lit.)
• Boiling Point: 577.4°Cat760mmHg
• Flash Point: 299.1°C
• PSA: 0.00000
• Density: 1.286g/cm³
• LogP: 6.40020
• XLogP3: 7.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 342.140850574
• Heavy Atom Count: 27
• Complexity: 492

Purity/Quality:

98%,99%, ^*data from raw suppliers

Truxene ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1C2=CC=CC=C2C3=C4CC5=CC=CC=C5C4=C6CC7=CC=CC=C7C6=C31

Technology Process of Truxene

There total 35 articles about Truxene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

inden-1-one (83-33-0) → truxene (548-35-6)

Guidance literature:

With hydrogenchloride; acetic acid; In water; at 100 ℃; for 16h;

DOI:10.1002/anie.201814388

Reference yield: 85.0%

truxenone (4430-15-3) → truxene (548-35-6)

Guidance literature:

With hydrazine hydrate; In diethylene glycol; at 180 ℃; for 24h; Temperature;

DOI:10.1016/j.tetlet.2013.11.080

Reference yield: 66.0%

3-(methylthio)indene (90474-54-7) + methyl iodide (74-88-4) → truxene (548-35-6)

Guidance literature:

In dichloromethane; for 12h; Heating;

upstream raw materials:

4b,4c,9b,9c-tetrahydro-cyclobuta[1,2-a;3,4-a']diindene-5,10-dione

truxenone

2,3-dihydro-3'H-[1,2']biindenyliden-1'-one

inden-1-one

Downstream raw materials:

2,7,12-tribromo-5,5',10,10',15,15'-hexahexyltruxene

2,7,12-tri-(4′,4′,5′,5′-tetramethyl-1′,3′,2′-dioxaborolane)hexaethyltruxene

Refernces

• 1、 Kotha, Sambasivarao,Ali, Rashid,Panguluri, Nageswara Rao,Datta, Anindya,Kannaujiya, Krishna K.. "Synthesis and photophysical properties of star-shaped blue green emitting π-conjugated spirotruxenes". . p. 4080 - 4085. Retrieved 2018.
• 2、 Zhang, Qiongqiong,Zhang, Cankun,Cao, Lingyun,Wang, Zi,An, Bing,Lin, Zekai,Huang, Ruiyun,Zhang, Zhiming,Wang, Cheng,Lin, Wenbin. "F?rster Energy Transport in Metal-Organic Frameworks Is beyond Step-by-Step Hopping". . p. 5308 - 5315. Retrieved 2016.
• 3、 Sharma, Rekha,Thomas, Michael B.,Misra, Rajneesh,D'Souza, Francis. "Strong Ground- and Excited-State Charge Transfer in C3-Symmetric Truxene-Derived Phenothiazine-Tetracyanobutadine and Expanded Conjugates". . p. 4350 - 4355. Retrieved 2019.
• 4、 Xie, Yuanpeng,Zhang, Xinfu,Xiao, Yi,Zhang, Youdi,Zhou, Fan,Qi, Jing,Qu, Junle. "Fusing three perylenebisimide branches and a truxene core into a star-shaped chromophore with strong two-photon excited fluorescence and high photostability". . p. 4338 - 4340. Retrieved 2012.
• 5、 Metz,G.. "-". . p. 614 - 615. Retrieved 1972.
• 6、 Kemp,Spanswick. "". . p. 2544. Retrieved 1967.
• 7、 Aktas, Ece,Jiménez-López, Jesús,Rodríguez-Seco, Cristina,Pudi, Rajesh,Ortu?o, Manuel A.,López, Núria,Palomares, Emilio. "Supramolecular Coordination of Pb2+ Defects in Hybrid Lead Halide Perovskite Films Using Truxene Derivatives as Lewis Base Interlayers". . p. 2702 - 2711. Retrieved 2019.
• 8、 Zhu, Jun-Long,Zhang, Dawei,Ronson, Tanya K.,Wang, Wenjing,Xu, Lin,Yang, Hai-Bo,Nitschke, Jonathan R.. "A Cavity-Tailored Metal-Organic Cage Entraps Gases Selectively in Solution and the Amorphous Solid State". . p. 11789 - 11792. Retrieved 2021.
• 9、 Ali, Rashid,Alvi, Shakeel. "Design, synthesis and photophysical properties of novel star-shaped truxene-based heterocycles utilizing ring-closing metathesis, Clauson–Kaas, Van Leusen and Ullmann-type reactions as key tools". . p. 1374 - 1384. Retrieved 2021/06/16.
• 10、 Alvi, Shakeel,Ali, Rashid. "An expeditious and highly efficient synthesis of substituted pyrroles using a low melting deep eutectic mixture". . p. 9732 - 9745. Retrieved 2021/12/01.