2,7,12-tribromo-5,5',10,10',15,15'-hexahexyltruxene

Base Information

• Chemical Name: 2,7,12-tribromo-5,5',10,10',15,15'-hexahexyltruxene
• CAS No.: 600172-86-9
• Molecular Formula: C₆₃H₈₇Br₃
• Molecular Weight: 1084.1
• Mol file: 600172-86-9.mol

Synonyms:2,7,12-tribromo-5,5',10,10',15,15'-hexahexyltruxene

Chemical Property of 2,7,12-tribromo-5,5',10,10',15,15'-hexahexyltruxene

Chemical Property:

• Boiling Point: 896.0±65.0 °C(Predicted)
• Density: 1.163±0.06 g/cm3(Predicted)

Purity/Quality:

HPLC≥98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,7,12-tribromo-5,5',10,10',15,15'-hexahexyltruxene

There total 6 articles about 2,7,12-tribromo-5,5',10,10',15,15'-hexahexyltruxene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.3%

5,5,10,10,15,15-hexahexyltruxene (600172-85-8) → 2,7,12-tribromo-5,5',10,10',15,15'-hexahexyltruxene (600172-86-9)

Guidance literature:

With bromine; In dichloromethane; at 20 ℃; for 24h;

Reference yield:

1-bromo-hexane (111-25-1) → 2,7,12-tribromo-5,5',10,10',15,15'-hexahexyltruxene (600172-86-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 83.2 percent / Br₂ / CH₂Cl₂ / 12 h

With bromine; In dichloromethane;

DOI:10.1021/ja039228n

Reference yield:

truxene (548-35-6) → 2,7,12-tribromo-5,5',10,10',15,15'-hexahexyltruxene (600172-86-9)

Guidance literature:

Multi-step reaction with 2 steps

1: n-butyllithium / -78 °C

2: bromine; potassium carbonate / 3 h / 20 °C

With n-butyllithium; bromine; potassium carbonate;

DOI:10.1039/c2cc31261a

upstream raw materials:

5,5,10,10,15,15-hexahexyltruxene

1-bromo-hexane

truxene

inden-1-one

Downstream raw materials:

2,7,12-tri-(4′,4′,5′,5′-tetramethyl-1′,3′,2′-dioxaborolane)hexaethyltruxene

2,7,12-tri-(2-acetylphenyl)-5,5',10,10',15,15'-hexahexyltruxene

C₁₁₇H₁₂₉N₃

4-[7,12-bis-(5-bromo-thiophen-2-yl)-5,5,10,10,15,15-hexahexyl-10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluoren-2-yl]-benzaldehyde

Refernces

• 1、 Xu, Hai-Jun,Du, Bin,Gros, Claude P.,Richard, Philippe,Barbe, Jean-Michel,Harvey, Pierre D.. "Shape-persistent poly-porphyrins assembled by a central truxene: Synthesis, structure, and singlet energy transfer behaviors". . p. 44 - 55. Retrieved 2013.
• 2、 -. "ORGANIC COMPOUND, LIGHT EMITTING DIODE AND LIGHT EMITTING DEVICE HAVING THE COMPOUND". Paragraph 0202-0203. . Retrieved 2020/07/05.
• 3、 Aktas, Ece,Jiménez-López, Jesús,Rodríguez-Seco, Cristina,Pudi, Rajesh,Ortu?o, Manuel A.,López, Núria,Palomares, Emilio. "Supramolecular Coordination of Pb2+ Defects in Hybrid Lead Halide Perovskite Films Using Truxene Derivatives as Lewis Base Interlayers". . p. 2702 - 2711. Retrieved 2019/07/05.