S-phenylmethyl thioformate

Base Information

• Chemical Name: S-phenylmethyl thioformate
• CAS No.: 32779-85-4
• Molecular Formula: C₈H₈OS
• Molecular Weight: 152.217
• Mol file: 32779-85-4.mol

Synonyms:S-phenylmethyl thioformate

Chemical Property of S-phenylmethyl thioformate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of S-phenylmethyl thioformate

There total 10 articles about S-phenylmethyl thioformate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

N-Phenyl-thioformimidic acid benzyl ester (84495-76-1) → S-phenylmethyl thioformate (32779-85-4)

Guidance literature:

With hydrogenchloride; In diethyl ether; for 0.166667h; Ambient temperature;

Reference yield: 65.0%

formic acid (64-18-6) + phenylmethanethiol (100-53-8) → S-phenylmethyl thioformate (32779-85-4)

Guidance literature:

With dicyclohexyl-carbodiimide; In ethyl acetate; at 0 ℃; for 2h;

DOI:10.1080/00397919208021120

Reference yield: 30.0%

bis(phenylmethylthio)(methylsulfinyl)methane → S-methyl methanethiosulfinate (13882-12-7) + S-phenylmethyl thioformate (32779-85-4) + tris(phenylmethylthio)methane (10606-38-9) + 1-benzyl-2-methyldisulfide (699-10-5)

Guidance literature:

for 192h; Ambient temperature;

DOI:10.1016/S0040-4020(96)01071-X

upstream raw materials:

thioformimidic acid benzyl ester; hydrochloride

phenylmethanethiol

formyl acetic anhydride

formic acid

Downstream raw materials:

benzyl dichloromethyl sulfide

benzyl trichloromethyl thioether

tris(phenylmethylthio)methane

Refernces

• 1、 Leriverend, Catherine,Metzner, Patrick,Capperucci, Antonella,Degl'Innocenti, Alessandro. "Thiophilic addition of organolithiums to trithiocarbonate oxides (sulfines). Synthesis of β-oxoketene dithioacetals, 1,4-dicarbonyl compounds, and allyl sulfoxides". . p. 1323 - 1342. Retrieved 2007/10/03.
• 2、 Matsubara, Yoshio,Nakamura, Toshiyuki,Yoshihara, Masakuni,Maeshima, Toshihishi. "A Novel Method for the Preparation of Thioformates and Thiols by using Thioformimidates". . p. 3389 - 3391. Retrieved 2007/10/02.