Technology Process of 2,3,6,2',3',6'-hexakis-O-(4-methoxyphenylmethyl)-β-D-lactoside
There total 6 articles about 2,3,6,2',3',6'-hexakis-O-(4-methoxyphenylmethyl)-β-D-lactoside which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
methyl 4',6'-O-(p-methoxybenzylidene)-2,3,6,2',3'-pentakis-O-(4-methoxyphenylmethyl)-β-D-lactoside;
With
aluminum (III) chloride; trimethylamine-borane;
In
tetrahydrofuran;
at 20 ℃;
for 3h;
Inert atmosphere;
Molecular sieve;
With
water; Rochelle's salt;
In
tetrahydrofuran;
at 20 ℃;
for 0.333333h;
DOI:10.1016/j.bmc.2011.04.048
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: toluene-4-sulfonic acid / N,N-dimethyl-formamide / 1 h / 70 °C / Inert atmosphere
2.1: sodium hydride / N,N-dimethyl-formamide / 0.17 h / 20 °C / Inert atmosphere
3.1: aluminum (III) chloride; trimethylamine-borane / tetrahydrofuran / 3 h / 20 °C / Inert atmosphere; Molecular sieve
3.2: 0.33 h / 20 °C
With
aluminum (III) chloride; trimethylamine-borane; sodium hydride; toluene-4-sulfonic acid;
In
tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1016/j.bmc.2011.04.048
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: sodium hydride / N,N-dimethyl-formamide / 0.17 h / 20 °C / Inert atmosphere
2.1: aluminum (III) chloride; trimethylamine-borane / tetrahydrofuran / 3 h / 20 °C / Inert atmosphere; Molecular sieve
2.2: 0.33 h / 20 °C
With
aluminum (III) chloride; trimethylamine-borane; sodium hydride;
In
tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1016/j.bmc.2011.04.048
