Technology Process of N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium hexafluorophosphate
There total 7 articles about N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium hexafluorophosphate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
potassium hexafluorophosphate;
In
dichloromethane; water;
Inert atmosphere;
DOI:10.1002/anie.201006218
- Guidance literature:
-
Multi-step reaction with 7 steps
1.1: N-chloro-succinimide / tetrachloromethane / 11 h / 20 °C
2.1: potassium fluoride; 18-crown-6 ether / acetonitrile / 168 h / Reflux
3.1: N-Bromosuccinimide; water / methanol / 0.5 h / 20 °C
4.1: sodium azide; sulfuric acid / chloroform / 0 - 20 °C / Inert atmosphere
5.1: dichloromethane / 0.5 h / 20 °C / Inert atmosphere
5.2: 1 h / 20 °C / Inert atmosphere
6.1: 11 h / 20 °C / Neat (no solvent); Inert atmosphere
7.1: potassium hexafluorophosphate / dichloromethane; water / Inert atmosphere
With
potassium hexafluorophosphate; potassium fluoride; N-chloro-succinimide; N-Bromosuccinimide; sodium azide; 18-crown-6 ether; sulfuric acid; water;
In
methanol; tetrachloromethane; dichloromethane; chloroform; water; acetonitrile;
DOI:10.1002/anie.201006218
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: dichloromethane / 0.5 h / 20 °C / Inert atmosphere
1.2: 1 h / 20 °C / Inert atmosphere
2.1: 11 h / 20 °C / Neat (no solvent); Inert atmosphere
3.1: potassium hexafluorophosphate / dichloromethane; water / Inert atmosphere
With
potassium hexafluorophosphate;
In
dichloromethane; water;
DOI:10.1002/anie.201006218
