Poly(N-vinylcarbazole)

Base Information

• Chemical Name: Poly(N-vinylcarbazole)
• CAS No.: 25067-59-8
• Molecular Formula: C₁₄H₁₁N
• Molecular Weight: 193.248
• Hs Code.: 29339900
• Mol file: 25067-59-8.mol

Synonyms:Poly(vinylcarbazole); Poly(9-vinyl-9H-carbazole); 9-Vinylcarbazole homopolymer; 9-Vinylcarbazole polymer

Chemical Property of Poly(N-vinylcarbazole)

Chemical Property:

• Appearance/Colour: white to cream powder
• Melting Point: >300oC
• Refractive Index: n20/D 1.683
• PSA: 4.93000
• Density: 1.2 g/mL at 25 °C(lit.)
• LogP: 3.89500

Purity/Quality:

Poly(N-vinylcarbazole) ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: PVK:graphene oxide composite can be used as a hybrid film which can be coated on silica substrate for the fabrication of organic field effect transistors (OFETs). It can also form a nano-composite film with carbon nanospheres (CNS) which can be potentially used in supercapacitors and sensor based applications.

Technology Process of Poly(N-vinylcarbazole)

There total 23 articles about Poly(N-vinylcarbazole) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.6%

potassium carbazole (33650-07-6) + acetylene (74-86-2,25067-58-7) → 9-vinyl-9H-carbazole (1484-13-5,25067-59-8)

Guidance literature:

at 160 ℃; for 2.5h; under 760.051 Torr; Time;

Reference yield: 96.0%

chloroethylene (75-01-4,9002-86-2) + 9H-carbazole (86-74-8,105184-46-1,97960-57-1) → 9-vinyl-9H-carbazole (1484-13-5,25067-59-8)

Guidance literature:

With bis(η3-allyl-μ-chloropalladium(II)); sodium hydroxide; tri tert-butylphosphoniumtetrafluoroborate; In toluene; at 100 ℃; for 10h; Reagent/catalyst; Inert atmosphere;

Reference yield: 95.0%

9H-carbazole (86-74-8,105184-46-1,97960-57-1) + acetylene (74-86-2,25067-58-7) → 9-vinyl-9H-carbazole (1484-13-5,25067-59-8)

Guidance literature:

With tributylphosphine; In N,N-dimethyl acetamide; at 140 ℃; for 16h; under 1.5 Torr; Glovebox; Sealed tube; Autoclave;

DOI:10.1021/acs.joc.1c01807

upstream raw materials:

2-carbazol-9-yl-ethanol

chloroethylene

potassium carbazole

9H-carbazole

Downstream raw materials:

9-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)ethyl)-9H-carbazole

trans-2-methyl-N-phenyl-1,2,3,4-tetrahydroquinolin-4-amine

cis-2-methyl-N-phenyl-1,2,3,4-tetrahydroquinolin-4-amine

cis-2,6-dimethyl-N-(p-methylphenyl)-1,2,3,4-tetrahydroquinolin-4-amine

Refernces

• 1、 Koh, Ming Joo,Lee, Boon Chong,Li, Ping,Zhang, Xiaoxiang. "Base-Mediated Site-Selective Hydroamination of Alkenes". supporting information. . Retrieved 2021/12/29.
• 2、 -. "Method for synthesizing N-vinylcarbazole". Paragraph 0014-0019. . Retrieved 2019/11/13.