Technology Process of 2,8-bis((4-(decyloxy)phenyl)ethynyl)dicyclopenta[de,mn]-tetracene
There total 3 articles about 2,8-bis((4-(decyloxy)phenyl)ethynyl)dicyclopenta[de,mn]-tetracene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
bis(benzonitrile)palladium(II) dichloride; copper(l) iodide; tri-tert-butyl phosphine; diisopropylamine;
In
toluene;
at 20 ℃;
for 6h;
DOI:10.1021/ja304602t
- Guidance literature:
-
Multi-step reaction with 3 steps
1: bis-triphenylphosphine-palladium(II) chloride; triethylamine; triphenylphosphine / benzene / 110 °C / Inert atmosphere
2: N-Bromosuccinimide / tetrahydrofuran-d8 / 0.75 h / 45 °C
3: bis(benzonitrile)palladium(II) dichloride; copper(l) iodide; tri-tert-butyl phosphine; diisopropylamine / toluene / 6 h / 20 °C
With
bis-triphenylphosphine-palladium(II) chloride; bis(benzonitrile)palladium(II) dichloride; N-Bromosuccinimide; copper(l) iodide; tri-tert-butyl phosphine; triethylamine; diisopropylamine; triphenylphosphine;
In
tetrahydrofuran-d8; toluene; benzene;
DOI:10.1021/ja304602t
- Guidance literature:
-
Multi-step reaction with 3 steps
1: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; triphenylphosphine / tetrahydrofuran / 18 h / 65 °C
2: methanol; potassium hydroxide / tetrahydrofuran; water
3: bis(benzonitrile)palladium(II) dichloride; copper(l) iodide; tri-tert-butyl phosphine; diisopropylamine / toluene / 6 h / 20 °C
With
methanol; bis-triphenylphosphine-palladium(II) chloride; bis(benzonitrile)palladium(II) dichloride; copper(l) iodide; tri-tert-butyl phosphine; triethylamine; diisopropylamine; triphenylphosphine; potassium hydroxide;
In
tetrahydrofuran; water; toluene;
DOI:10.1021/ja304602t