RuH(η5-4-tert-butylphenoxide)(PPh3)2

Base Information

• Chemical Name: RuH(η5-4-tert-butylphenoxide)(PPh3)2
• CAS No.: 613265-07-9
• Molecular Formula: C₄₆H₄₄OP₂Ru
• Molecular Weight: 775.872
• Mol file: 613265-07-9.mol

Synonyms:RuH(η5-4-tert-butylphenoxide)(PPh3)2

Chemical Property of RuH(η5-4-tert-butylphenoxide)(PPh3)2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of RuH(η5-4-tert-butylphenoxide)(PPh3)2

There total 4 articles about RuH(η5-4-tert-butylphenoxide)(PPh3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

hydridochlorotris(triphenylphosphine)ruthenium(II) (55102-19-7) + potassium 4-(tert-butyl)phenolate (3130-29-8) → RuH(η5-4-tert-butylphenoxide)(PPh3)2 (613265-07-9)

Guidance literature:

In dichloromethane; under N2; solid K compd. added to stirred soln. of Ru complex (molar ratio 1:1) in CH2Cl2; stirred at room temp. for 2 h; filtered through Celite; concd.; treated with cold hexanes; ppt. reprecipitated from benzene-hexanes; elem. anal.;

DOI:10.1016/S0020-1693(02)01347-6

Reference yield:

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + deuteromethanol (1455-13-6) + potassium 4-(tert-butyl)phenolate (3130-29-8) → carbonyldihydridotris(triphenylphosphine)ruthenium(II) (22337-78-6) + RuH(η5-4-tert-butylphenoxide)(PPh3)2 (613265-07-9) + carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) (157072-60-1,166941-05-5,16971-33-8,61521-25-3)

Guidance literature:

In dichloromethane; deuteromethanol; byproducts: 4-t-BuC6H4OD; under N2; K compd. in MeOD added to soln. of Ru complex (molar ratio 2:1) in CH2Cl2; 24 h at room temp.; not isolated; detd. by (2)H and (1)H NMR spectra;

DOI:10.1016/S0020-1693(02)01347-6

Reference yield:

methanol (67-56-1) + tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + potassium 4-(tert-butyl)phenolate (3130-29-8) → carbonyldihydridotris(triphenylphosphine)ruthenium(II) (22337-78-6) + RuH(η5-4-tert-butylphenoxide)(PPh3)2 (613265-07-9)

Guidance literature:

In methanol; dichloromethane; under N2; K compd. in MeOH added to soln. of Ru complex (molar ratio 2:1) in CH2Cl2; 15 min at room temp.; not isolated; detd. by NMR spectra; Ru-(η5-ArO) and Ru-CO complexes (1:3) obtained;

DOI:10.1016/S0020-1693(02)01347-6

upstream raw materials:

methanol

tris(triphenylphosphine)ruthenium(II) chloride

dichloromethane

potassium 4-(tert-butyl)phenolate

Downstream raw materials:

[Ru(η6-4-tert-butylphenol)(PPh3)2]Cl

Refernces