potassium p-tert-butylphenolate

Base Information

• Chemical Name: potassium p-tert-butylphenolate
• CAS No.: 3130-29-8
• Molecular Formula: C10H14 O . K
• Molecular Weight: 188.311
• Hs Code.: 2907199090
• Mol file: 3130-29-8.mol

Synonyms:Phenol,4-(1,1-dimethylethyl)-, potassium salt (9CI); Phenol, p-tert-butyl-, potassiumsalt (8CI); Potassium, (p-tert-butylphenoxy)- (7CI); Potassium4-tert-butylphenoxide; Potassium p-tert-butylphenolate; Potassiump-tert-butylphenoxide; p-tert-Butylphenol potassium salt

Chemical Property of potassium p-tert-butylphenolate

Chemical Property:

• Vapor Pressure: 0.0361mmHg at 25°C
• Boiling Point: 233.7°Cat760mmHg
• Flash Point: 110.9°C
• PSA: 23.06000
• Density: g/cm³
• LogP: 3.12790

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of potassium p-tert-butylphenolate

There total 1 articles about potassium p-tert-butylphenolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

para-tert-butylphenol (98-54-4) → potassium 4-(tert-butyl)phenolate (3130-29-8)

Guidance literature:

With potassium hydroxide; In water;

DOI:10.1021/acs.joc.9b01485

Reference yield: 99.0%

2,2'-bis-(bromomethyl)-1,1'-biphenyl (38274-14-5) + potassium 4-(tert-butyl)phenolate (3130-29-8) → 2,2'-bis{[4-(tert-butyl)phenoxy]methyl}-1,1'-biphenyl

Guidance literature:

In N,N-dimethyl-formamide; for 0.25h; Reflux;

DOI:10.1021/acs.orglett.1c00087

Reference yield: 98.0%

potassium 4-(tert-butyl)phenolate (3130-29-8) + α,α'-dibromo-o-xylene (91-13-4) → 1,2-bis{[4-(tert-butyl)phenoxy]methyl}benzene

Guidance literature:

In N,N-dimethyl-formamide; for 0.25h; Reflux;

DOI:10.1021/acs.orglett.1c00087

upstream raw materials:

para-tert-butylphenol

Downstream raw materials:

3-oxo-3-phenylpropionic acid

carbonyldihydridotris(triphenylphosphine)ruthenium(II)

RuH(η5-4-tert-butylphenoxide)(PPh3)2

[Ru(η6-4-tert-butylphenol)(PPh3)2]Cl

Refernces

• 1、 Li, Lizhong,Zhou, Chunge,Liu, Minhua,Zhang, Ping,Zhang, Ning,Li, Jianming,Li, Tao,Liu, Xingping,Cheng, Shufen,Li, Qianhe,Liu, Aiping. "Design, synthesis, insecticidal, and acaricidal activities of novel pyrimidinamine derivatives containing a biphenyl ether". . p. 3206 - 3214. Retrieved 2019/11/13.