Chlorate

Base Information

• Chemical Name: Chlorate
• CAS No.: 14866-68-3
• Molecular Formula: ClO₃
• Molecular Weight: 83.4512
• UN Number: 1461
• UNII: 08Z8093742
• DSSTox Substance ID: DTXSID3073137
• Nikkaji Number: J1.587.838J
• Wikipedia: Chlorate
• Wikidata: Q217813
• RXCUI: 1546390
• Mol file: 14866-68-3.mol

Synonyms:Chlorate;Chlorates

Chemical Property of Chlorate

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 57.20000
• Density: g/cm³
• LogP: 0.33310
• XLogP3: 1.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 82.9535966
• Heavy Atom Count: 4
• Complexity: 36.5
• Transport DOT Label: Oxidizer

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Other Inorganic Compounds
• Canonical SMILES: [O-]Cl(=O)=O

Technology Process of Chlorate

There total 86 articles about Chlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 9.0%

sodium chlorite (7758-19-2) + hydrogen cation → chlorine dioxide (10049-04-4,25052-55-5) + chloride (16887-00-6) + oxygen (80937-33-3) + chlorate (14866-68-3,80434-34-0)

Guidance literature:

In water; at 60°C and pH = 2.4;;

Reference yield:

sodium perchlorate → chlorine dioxide (10049-04-4,25052-55-5) + chlorite (14998-27-7) + chloride (16887-00-6) + chlorate (14866-68-3,80434-34-0)

Guidance literature:

In water; other Radiation; γ-radiation of 1 - 8 M NaClO4 soln. at -38 - -196°C;;

Reference yield:

sodium perchlorate → chlorine dioxide (10049-04-4,25052-55-5) + chlorite (14998-27-7) + chloride (16887-00-6) + dihydrogen peroxide (7722-84-1) + chlorate (14866-68-3,80434-34-0)

Guidance literature:

In water; other Radiation; γ-radiation of concd. NaClO4 soln.; influence of NaClO4 concn.;; Kinetics;

DOI:10.1021/j100863a033

upstream raw materials:

sodium chlorite

ozone

perchloric acid

potassium chlorate

Downstream raw materials:

chloride

iodate

perchloric acid

chloric acid

Refernces

• 1、 Taube, H.. "". . p. 656 - 665. Retrieved 1957.
• 2、 Skrabal, A.,Skrabal, R.. "". . . Retrieved 1938.
• 3、 Rabat, Gyula,Kovacs, Klara M.. "Photoinduced reaction between chlorine dioxide and iodine in acidic aqueous solution". . p. 6167 - 6170. Retrieved 2001.
• 4、 Odeh, Ihab N.,Francisco, Joseph S.,Margerum, Dale W.. "New pathways for chlorine dioxide decomposition in basic solution". . p. 6500 - 6506. Retrieved 2002.
• 5、 Abel, A.. "". . . Retrieved 1951.
• 6、 Sizeneva,Kondrashova,Val'tsifer. "Spontaneous decomposition of industrially manufactured sodium hypochlorite solutions". . p. 541 - 545. Retrieved 2005.
• 7、 Chapin, R. M.. "". . p. 2211 - 2215. Retrieved 1934.
• 8、 Wang, Lu,Nicoson, Jeffrey S.,Huff Hartz, Kara E.,Francisco, Joseph S.,Margerum, Dale W.. "Bromite ion catalysis of the disproportionation of chlorine dioxide with nucleophile assistance of electron-transfer reactions between ClO2 and BrO2 in basic solution". . p. 108 - 113. Retrieved 2002.
• 9、 Skrabal, A.. "". . . Retrieved 1939.
• 10、 Vlatkovich, M.,Aten, A. H. W.. "". . p. 139 - 146. Retrieved 1962.