Hexyl methacrylate

Base Information

• Chemical Name: Hexyl methacrylate
• CAS No.: 142-09-6
• Molecular Formula: C10H18O2
• Molecular Weight: 170.252
• Hs Code.: 29161400
• European Community (EC) Number: 205-521-9
• NSC Number: 24169
• UN Number: 3082
• UNII: 538B2Q3HSV
• DSSTox Substance ID: DTXSID4025406
• Nikkaji Number: J47.830J
• Wikidata: Q27261083
• Metabolomics Workbench ID: 123468
• ChEMBL ID: CHEMBL1422108
• Mol file: 142-09-6.mol

Synonyms:hexyl methacrylate

Chemical Property of Hexyl methacrylate

Chemical Property:

• Appearance/Colour: clear colorless liquid
• Vapor Pressure: 2.21mmHg at 25°C
• Melting Point: -59--55°C
• Refractive Index: 1.4310
• Boiling Point: 161.999 °C at 760 mmHg
• Flash Point: 72.106 °C
• PSA: 26.30000
• Density: 0.887 g/cm³
• LogP: 2.68600
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Solubility.: soluble in Benzene,Acetone,Ether,Ethanol
• Water Solubility.: 29.9mg/L at 20℃
• XLogP3: 4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 7
• Exact Mass: 170.130679813
• Heavy Atom Count: 12
• Complexity: 150
• Transport DOT Label: Class 9

Purity/Quality:

99.9% ^*data from raw suppliers

Hexyl methacrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38-51/53-43
• Safety Statements: 26-36-36/37-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Plastics & Rubber -> (Meth)acrylates
• Canonical SMILES: CCCCCCOC(=O)C(=C)C
• Uses: Monomer for plastics, molding powder, solvent coatings, adhesives, oil additives; emulsions for textile, leather, and paper finishing. Hexyl Methacrylate can be used as a method for producing embedded or hybrid hydrogel contact lenses.

Technology Process of Hexyl methacrylate

There total 7 articles about Hexyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.0%

vinyl methacrylate (4245-37-8,25719-55-5) + hexan-1-ol (111-27-3) → 2-methyl-2-propenoic acid, hexyl ester (142-09-6,25087-17-6)

Guidance literature:

In 2,2,4-trimethylpentane; at 37 ℃; immobilized lipase from Candida cylindracea;

DOI:10.1016/0040-4039(91)80427-8

Reference yield:

Methacryloyl chloride (920-46-7,26937-45-1) + hexan-1-ol (111-27-3) → 2-methyl-2-propenoic acid, hexyl ester (142-09-6,25087-17-6)

Guidance literature:

With N,N,N'N'-tetramethyl-1,3-propanediamine; In acetonitrile; at 20 ℃;

DOI:10.1016/j.bmcl.2015.05.014

Reference yield:

methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) → 2-methyl-2-propenoic acid, hexyl ester (142-09-6,25087-17-6)

Guidance literature:

upstream raw materials:

α-hydroxy-isobutyric acid hexyl ester

methacrylic acid methyl ester

hexan-1-ol

poly(methacrylic acid)

Downstream raw materials:

furan-2-ylmethyl methacrylate

Refernces

• 1、 -. "Nail varnish composition comprising at least one film-forming gradient copolymer and cosmetic process for making up and/or caring for the nails". . . Retrieved 2008/06/13.
• 2、 Ikeda, Isao,Tanaka, Jun,Suzuki, Kimihiro. "SYNTHESIS OF ACRYLIC ESTERS BY LIPASE". . p. 6865 - 6866. Retrieved 2007/10/02.