Heptyl hydroperoxide

Base Information

• Chemical Name: Heptyl hydroperoxide
• CAS No.: 764-81-8
• Molecular Formula: C7H16O2
• Molecular Weight: 132.203
• Mol file: 764-81-8.mol

Synonyms:n-heptylhydroperoxyde;Hydroperoxide,heptyl;Heptylhydroperoxid;Heptyl-hydrogenperoxid;Heptyl hydroperoxide;1-heptyl hydroperoxide;1-hydroperoxy heptane;

Chemical Property of Heptyl hydroperoxide

Chemical Property:

• Vapor Pressure: 0.0674mmHg at 25°C
• Melting Point: 35.5°C
• Refractive Index: 1.4500 (estimate)
• Boiling Point: 203.4°C at 760 mmHg
• Flash Point: 76.8°C
• PSA: 29.46000
• Density: 0.893g/cm³
• LogP: 2.44640

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Heptyl hydroperoxide

There total 8 articles about Heptyl hydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

2-methoxyprop-2-yl hept-1-yl peroxide → 1-heptyl hydroperoxide (764-81-8,51728-68-8)

Guidance literature:

With acetic acid;

DOI:10.1016/S0014-827X(02)01238-7

Reference yield:

n-heptane (142-82-5) → n-pentyl methyl ketone (110-43-0) + 1-methylhexyl-hydroperoxide (762-46-9) + 1-heptyl hydroperoxide (764-81-8,51728-68-8) + 3-heptyl hydroperoxide (761-70-6) + 4-heptyl hydroperoxide (761-40-0) + heptan-3-one (106-35-4)

Guidance literature:

With 2-pyrazylcarboxylic acid; dihydrogen peroxide; oxygen; [n-Bu₄N]VO₃; In acetonitrile; at 23 ℃; for 24h; Product distribution; Mechanism; other alkanes; var. time, with or without H₂O and irradiation;

DOI:10.1016/0040-4020(96)00769-7

Reference yield:

→ 1-heptyl hydroperoxide (764-81-8,51728-68-8)

Guidance literature:

With diethyl ether; oxygen; at -60 ℃;

DOI:10.1021/ja01627a069 DOI:10.1177/107110070202300608

upstream raw materials:

heptyl methanesulfonate

n-heptylmagnesium chloride

n-heptane

dihydrogen peroxide

Downstream raw materials:

n-heptan1ol

1-Chloroheptane

heptanal

oenanthic acid

Refernces

• 1、 Cointeaux,Berrien,Camuzat-Dedenis,Peyrou,Provot,Bories,Loiseau,Mayrargue. "Synthesis and trichomonacidal activity of perketals and hydroperoxides". . p. 457 - 462. Retrieved 2007/10/03.
• 2、 Guerreiro,Schuchardt,Shul'pin. "Oxidation with the "O2-H2O2-VO3 --pyrazine-2-carboxylic acid" reagent: 6. * Oxidation of n-heptane and cyclohexane. Direct determination of alkyl hydroperoxides by gas-liquid chromatography". . p. 749 - 754. Retrieved 2007/10/03.