Dodecyl formate

Base Information

• Chemical Name: Dodecyl formate
• CAS No.: 28303-42-6
• Molecular Formula: C13H26O2
• Molecular Weight: 214.348
• Hs Code.: 2915120000
• European Community (EC) Number: 248-952-8
• UNII: D5ZBL62BWS
• DSSTox Substance ID: DTXSID40182556
• Nikkaji Number: J183.092I
• Wikidata: Q63395639
• Metabolomics Workbench ID: 4054
• Mol file: 28303-42-6.mol

Synonyms:Dodecyl formate;28303-42-6;Formic acid, dodecyl ester;EINECS 248-952-8;AI3-05909;WE(12:0/1:0);DODECYLFORMATE;dodecyl ormate;Formic acid dodecyl ester;D5ZBL62BWS;SCHEMBL68308;DTXSID40182556;CHEBI:180114;LMFA07010409;AS-79211;D93435;Q63395639

Chemical Property of Dodecyl formate

Chemical Property:

• Vapor Pressure: 0.0049mmHg at 25°C
• Melting Point: -19.1°C (estimate)
• Refractive Index: 1.4243 (estimate)
• Boiling Point: 276.1°Cat760mmHg
• Flash Point: 123.2°C
• PSA: 26.30000
• Density: 0.868g/cm³
• LogP: 4.71620
• XLogP3: 5.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 12
• Exact Mass: 214.193280068
• Heavy Atom Count: 15
• Complexity: 124

Purity/Quality:

98%Min ^*data from raw suppliers

DODECYL FORMATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCOC=O

Technology Process of Dodecyl formate

There total 15 articles about Dodecyl formate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

formic acid (64-18-6) + 1-dodecyl alcohol (112-53-8) → formiate de lauryle (28303-42-6)

Guidance literature:

toluene-4-sulfonic acid; at 85 ℃; for 4h;

DOI:10.1021/js980210y

Reference yield: 100.0%

1-dodecyl alcohol (112-53-8) + formic acid ethyl ester (109-94-4) → formiate de lauryle (28303-42-6)

Guidance literature:

cerium (IV) sulfate; silica gel; for 1h; Heating;

Reference yield: 93.0%

1-dodecyl alcohol (112-53-8) + chloral (75-87-6) → formiate de lauryle (28303-42-6)

Guidance literature:

With potassium carbonate; In acetone; at 25 ℃; for 5h;

DOI:10.1016/S0040-4020(02)00185-0

upstream raw materials:

formic acid

1-dodecyl alcohol

dodecyl phenyl selenide

N,N-dimethyl-formamide

Downstream raw materials:

1-dodecyl alcohol

Refernces

• 1、 Hilt, Gerhard,Huy, Peter H.,Kohlmeyer, Corinna,Sch?fer, André. "Formamide-Catalyzed Nucleophilic Substitutions: Mechanistic Insight and Rationalization of Catalytic Activity". . p. 11567 - 11577. Retrieved 2020/11/17.
• 2、 Huy, Peter H.,Filbrich, Isabel. "A General Catalytic Method for Highly Cost- and Atom-Efficient Nucleophilic Substitutions". supporting information. p. 7410 - 7416. Retrieved 2018/04/30.