Carbonic acid 1-phenylethylene ester

Base Information

• Chemical Name: Carbonic acid 1-phenylethylene ester
• CAS No.: 4427-92-3
• Molecular Formula: C9H8O3
• Molecular Weight: 164.161
• Hs Code.: 2932999099
• Mol file: 4427-92-3.mol

Synonyms:1-Phenyl-1, 2-ethylene carbonate;4-phenyl-1,3-dioxolan-2-one;Carbonic acid, cyclic phenylethylene ester;1,3-Dioxolan-2-one, 4-phenyl-;Cyclic phenylethylene carbonate;

Chemical Property of Carbonic acid 1-phenylethylene ester

Chemical Property:

• Vapor Pressure: 3.26E-05mmHg at 25°C
• Melting Point: 56-57 °C
• Refractive Index: 1.545
• Boiling Point: 354.821 °C at 760 mmHg
• Flash Point: 171.072 °C
• PSA: 35.53000
• Density: 1.249 g/cm³
• LogP: 1.89450
• Storage Temp.: -20°C Freezer, Under inert atmosphere
• Solubility.: Chloroform (Slightly), Methanol (Slightly)

Purity/Quality:

99.5% ^*data from raw suppliers

4-phenyl-1,3-dioxolan-2-one ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Carbonic acid 1-phenylethylene ester

There total 115 articles about Carbonic acid 1-phenylethylene ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

phenylethane 1,2-diol (93-56-1) + carbon dioxide (124-38-9,18923-20-1) + 2-methyl-but-3-yn-2-ol (115-19-5) → 4-Phenyl-1,3-dioxolan-2-one (4427-92-3) + 3-Hydroxy-3-methyl-2-butanone (115-22-0)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; zinc(II) chloride; In acetonitrile; at 80 ℃; for 24h; under 15001.5 Torr; chemoselective reaction; Autoclave; Sealed tube;

DOI:10.1055/s-0037-1611058

Reference yield: 98.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + carbon dioxide (124-38-9,18923-20-1) → 4-Phenyl-1,3-dioxolan-2-one (4427-92-3)

Guidance literature:

With tert.-butylhydroperoxide; at 80 ℃; for 10h; under 15001.5 Torr; Reagent/catalyst; Time; Autoclave;

DOI:10.1039/c9nj05513d

Reference yield: 98.0%

phenylethane 1,2-diol (93-56-1) + Diethyl carbonate (105-58-8,76619-83-5) → 4-Phenyl-1,3-dioxolan-2-one (4427-92-3)

Guidance literature:

With aluminum oxide; cesium fluoride; at 129.85 ℃; for 0.416667h;

DOI:10.1016/j.jcat.2004.10.024

upstream raw materials:

styrene oxide

carbamic acid-(β-chloro-phenethyl ester)

phenylethane 1,2-diol

Diethyl carbonate

Downstream raw materials:

styrene oxide

carbon dioxide

2-phenylethanol

2-methoxy-2-phenylethanol

Refernces

• 1、 Cho, Hye-Young,Yang, Da-Ae,Kim, Jun,Jeong, Soon-Yong,Ahn, Wha-Seung. "CO2 adsorption and catalytic application of Co-MOF-74 synthesized by microwave heating". . p. 35 - 40. Retrieved 2012.
• 2、 Ullah, Habib,Mousavi, Bibimaryam,Younus, Hussein A.,Khattak, Zafar A.K.,Suleman, Suleman,Jan, Muhammad T.,Yu, Baoyi,Chaemchuen, Somboon,Verpoort, Francis. "ONO pincer type ligand complexes of Al(III) as efficient catalyst for chemical fixation of CO2 to epoxides at atmospheric pressure". . p. 190 - 198. Retrieved 2019.
• 3、 Velásquez-Hernández, Miriam de J.,Torres-Huerta, Aarón,Hernández-Balderas, Uvaldo,Martínez-Otero, Diego,Nú?ez-Pineda, Alejandra,Jancik, Vojtech. "Novel route to silanetriols and silanediols based on acetoxysilylalkoxides". . p. 161 - 171. Retrieved 2017.
• 4、 Alvaro, Mercedes,Baleizao, Carlos,Carbonell, Esther,El Ghoul, Mostafa,García, Hermenegildo,Gigante, Barbara. "Polymer-bound aluminium salen complex as reusable catalysts for CO 2 insertion into epoxides". . p. 12131 - 12139. Retrieved 2005.
• 5、 Qiu, Renhua,Meng, Zhengong,Yin, Shuangfeng,Song, Xingxing,Tan, Nianyuan,Zhou, Yongbo,Yu, Kun,Xu, Xinhua,Luo, Shenglian,Au, Chak-Tong,Wong, Wai-Yeung. "Synthesis and structure of binuclear O/S-bridged organobismuth complexes and their cooperative catalytic effect on CO2 fixation". . p. 404 - 410. Retrieved 2012.
• 6、 Hu, Yu Lin,Xing, Rong. "Highly Efficient and Convenient Supported Ionic Liquid TiCl5-DMIL@SiO2@Fe3O4-Catalyzed Cycloaddition of CO2 and Epoxides to Cyclic Carbonates". . p. 1453 - 1463. Retrieved 2017.
• 7、 Zhao, Qing-Ning,Song, Qing-Wen,Liu, Ping,Zhang, Qian-Xia,Gao, Jun-Hua,Zhang, Kan. "Catalytic Conversion of CO2 to Cyclic Carbonates through Multifunctional Zinc-Modified ZSM-5 Zeolite". . p. 187 - 193. Retrieved 2018.
• 8、 Boisselier, Veronique Le,Postel, Michele,Dunach, Elisabet. "BiBr3-catalysed formation of cyclic carbonates from epoxides and DMF: a new oxidation reaction with molecular oxygen". . p. 95 - 96. Retrieved 1997.
• 9、 Senthilkumar,Maru, Minaxi S.,Somani,Bajaj,Neogi, Subhadip. "Unprecedented NH2-MIL-101(Al)/n-Bu4NBr system as solvent-free heterogeneous catalyst for efficient synthesis of cyclic carbonates via CO2 cycloaddition". . p. 418 - 428. Retrieved 2018.
• 10、 Khaligh, Nader Ghaffari,Mihankhah, Taraneh,Johan, Mohd Rafie. "Efficient chemical fixation of CO2 into cyclic carbonates using poly(4-vinylpyridine) supported iodine as an eco-friendly and reusable heterogeneous catalyst". . . Retrieved 2018.