FLUOROCYCLOPENTANE

Base Information

• Chemical Name: FLUOROCYCLOPENTANE
• CAS No.: 1481-36-3
• Molecular Formula: C5H9 F
• Molecular Weight: 88.1249
• Hs Code.: 2903890090
• Mol file: 1481-36-3.mol

Synonyms:Cyclopentylfluoride; Fluorocyclopentane

Chemical Property of FLUOROCYCLOPENTANE

Chemical Property:

• Vapor Pressure: 150mmHg at 25°C
• Refractive Index: 1.3910 to 1.3950
• Boiling Point: 68.8°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 0.9g/cm³
• LogP: 1.89850

Purity/Quality:

98%,99%, ^*data from raw suppliers

Fluorocyclopentane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of FLUOROCYCLOPENTANE

There total 12 articles about FLUOROCYCLOPENTANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

cyclopentene (142-29-0) → fluorocyclopentane (1481-36-3)

Guidance literature:

With HF-melamine; hydrogen fluoride; In tetrahydrofuran; at 0 ℃; for 1h;

DOI:10.1246/cl.1983.1135

Reference yield: 80.0%

cyclopentyl chloride (930-28-9) → fluorocyclopentane (1481-36-3)

Guidance literature:

With potassium fluoride; tetrakis[tris(dimethylamino)phosphoranylideneamino]phosphonium chloride; tris phosphate; In DMF (N,N-dimethyl-formamide); at 110 ℃; for 6h;

Reference yield: 77.0%

hexafluorophosphazene (15599-91-4) + dimethyl amine (124-40-3) + cyclopentene (142-29-0) → fluorocyclopentane (1481-36-3) + Dimethylaminopentafluorocyclotriphosphonitril (23208-17-5)

Guidance literature:

In acetonitrile; at -10 - 0 ℃; for 1h; Inert atmosphere;

upstream raw materials:

fluorocarbonic acid cyclopentyl ester

cyclopentene

Cyclopentanol

Cyclopentyl bromide

Refernces

• 1、 Rogers,Roberts. "-". . p. 843,844. Retrieved 1946.
• 2、 West, Julian G.,Bedell, T. Aaron,Sorensen, Erik J.. "The Uranyl Cation as a Visible-Light Photocatalyst for C(sp3)?H Fluorination". . p. 8923 - 8927. Retrieved 2016.
• 3、 González-Esguevillas, María,Miró, Javier,Jeffrey, Jenna L.,MacMillan, David W.C.. "Photoredox-catalyzed deoxyfluorination of activated alcohols with Selectfluor". supporting information. p. 4222 - 4227. Retrieved 2019/06/13.