Hexafluorocyclotriphosphazene

Base Information

• Chemical Name: Hexafluorocyclotriphosphazene
• CAS No.: 15599-91-4
• Molecular Formula: F6N3 P3
• Molecular Weight: 248.932
• Hs Code.: 29319019
• European Community (EC) Number: 621-138-3
• DSSTox Substance ID: DTXSID40166013
• Nikkaji Number: J713.549A
• Wikidata: Q72499236
• Mol file: 15599-91-4.mol

Synonyms:Hexafluorocyclotriphosphazene;15599-91-4;2,2,4,4,6,6-hexafluoro-1,3,5-triaza-2lambda5,4lambda5,6lambda5-triphosphacyclohexa-1,3,5-triene;Phosphonitrilefluoridetrimer;1,3,5,2,4,6-Triazatriphosphorine, hexafluoro-;Phosphonitrile fluoride trimer;DTXSID40166013;MFCD00192400;1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexafluoro-2,2,4,4,6,6,-hexahydro-;FT-0654869;H1429;A809708;1,3,5,2,4,6-Triazatriphosphorine,2,2,4,4,6,6-hexafluoro-2,2,4,4,6,6,-hexahydro-

Chemical Property of Hexafluorocyclotriphosphazene

Chemical Property:

• Melting Point: 25-30 °C(lit.)
• Refractive Index: 1.3183 (589.3 nm 32℃)
• Boiling Point: 50.9 °C(lit.)
• PKA: -27.34±0.27(Predicted)
• Flash Point: °C
• PSA: 66.51000
• Density: 2.56g/cm³
• LogP: 3.96240
• Storage Temp.: 2-8°C
• Solubility.: soluble in Toluene
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 0
• Exact Mass: 248.92092698
• Heavy Atom Count: 12
• Complexity: 252

Purity/Quality:

98% ^*data from raw suppliers

Hexafluorocyclotriphosphazene ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: N1=P(N=P(N=P1(F)F)(F)F)(F)F

Technology Process of Hexafluorocyclotriphosphazene

There total 17 articles about Hexafluorocyclotriphosphazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.8%

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine (940-71-6,16422-79-0) + sodium fluoride (7681-49-4) → hexafluorophosphazene (15599-91-4)

Guidance literature:

With 1-butyl-3-methylimidazolium Tetrafluoroborate; In N,N-dimethyl-formamide; at 50 ℃; for 5h; Reagent/catalyst; Solvent; Temperature;

Reference yield: 98.7%

potassium fluoride (7789-23-3) + 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine (940-71-6,16422-79-0) → hexafluorophosphazene (15599-91-4)

Guidance literature:

With 4-n-butyl-4-methylmorpholinium hydroxide; In acetonitrile; at 30 ℃; for 2h; Temperature; Solvent; Reagent/catalyst; Ionic liquid;

Reference yield: 97.2%

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine (940-71-6,16422-79-0) → hexafluorophosphazene (15599-91-4)

Guidance literature:

With potassium fluoride; Triethylene glycol dimethyl ether; ethanol; In hexane; at 0 - 30 ℃; for 2h; Solvent; Reagent/catalyst; Temperature;

upstream raw materials:

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

silver fluoride

nitrogen trifluoride

CF₃SF₅

Downstream raw materials:

cyclopentadienyl iron(II) dicarbonyl dimer

1,1-bis(dicarbonylcyclopentadienyliron)-3,3,5,5-tetrafluorocyclotriphosphazene

ethoxy(pentafluoro)cyclotriphosphazene

fluorocyclopentane

Refernces

• 1、 Burg, A. B.,Caron, A. P.. "". . p. 836 - 838. Retrieved 1959.
• 2、 Walsh et al.. "". . p. L9. Retrieved 1976.
• 3、 -. "Preparation method of hexafluorocyclotriphosphazene". Paragraph 0019-0028. . Retrieved 2021/06/23.
• 4、 -. "Preparation method of pentafluoro ethoxy cyclotriphosphazene". Paragraph 0049; 0059-0081. . Retrieved 2019/08/15.