iron di(thiocyanate)

Base Information

• Chemical Name: iron di(thiocyanate)
• CAS No.: 6010-09-9
• Molecular Formula: 3CNS*Fe
• Molecular Weight: 230.098
• Mol file: 6010-09-9.mol

Synonyms:Ironthiocyanate (6CI); Iron thiocyanate (Fe(SCN)2) (7CI); Ferrous thiocyanate; Ironbis(thiocyanate); Iron dithiocyanate; Iron(2+) thiocyanate; Iron(II)thiocyanate

Chemical Property of iron di(thiocyanate)

Chemical Property:

• Vapor Pressure: 4.73mmHg at 25°C
• Boiling Point: 146°C at 760 mmHg
• Flash Point: 42.1°C
• PSA: 125.18000
• LogP: 0.79206
• Water Solubility.: soluble H2O, alcohol, ether [MER06]

Purity/Quality:

99% ^*data from raw suppliers

FERROUS THIOCYANATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Physical Properties: Pale-green monoclinic prisms; unstable; readily oxidized on exposure to air; decomposes on heating; very soluble in water; also soluble in alcohol and ether.
• Uses: iron di(thiocyanate) is used as an analytical reagent and as an indicator for detecting peroxides in organic solutions Iron(II) thiocyanate is used as an analytical reagent and as an indicator for detecting peroxides in organic solutions.

Technology Process of iron di(thiocyanate)

There total 52 articles about iron di(thiocyanate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iron(III) chloride hexahydrate + potassium thioacyanate (333-20-0) → iron(III) thiocyanate (4119-52-2,6010-09-9,16998-54-2,127795-40-8)

Guidance literature:

In methanol;

DOI:10.1016/j.ica.2014.01.032

Reference yield:

ammonium thiocyanate + iron(III) chloride (7705-08-0) → iron(III) thiocyanate (4119-52-2,6010-09-9,16998-54-2,127795-40-8)

Guidance literature:

In further solvent(s); reaction in abs. isoamyl alcohol;;

Reference yield:

iron(III) sulfate + potassium thioacyanate (333-20-0) → iron(III) thiocyanate (4119-52-2,6010-09-9,16998-54-2,127795-40-8)

Guidance literature:

In sulfuric acid; no reaction in 100% H2SO4;;

upstream raw materials:

potassium thioacyanate

iron(III)

Thiocyanate

iron(II) thiocyanate

Downstream raw materials:

iodine

sodium thiocyanide

hydrogen sulfide

Sulfate

Refernces

• 1、 Bonnet, Sylvestre,Spa, Silvia,Zheng, Sipeng,van Geest, Erik P.,van Ruitenbeek, Jan M.. "Highly Ordered, Self-Assembled Monolayers of a Spin-Crossover Complex with In-Plane Interactions". . p. 2814 - 2821. Retrieved 2021/07/07.
• 2、 Bassey, Euan N.,Cliffe, Matthew J.,Da Silva, Ivan,Dutton, Sian E.,Grey, Clare P.,Keyzer, Evan N.,Lee, Jeongjae,Manuel, Pascal,Paddison, Joseph A. M.. "Strengthening the Magnetic Interactions in Pseudobinary First-Row Transition Metal Thiocyanates, M(NCS)2". supporting information. p. 11627 - 11639. Retrieved 2020/09/09.