titanium(III) trichloride

Base Information

• Chemical Name: titanium(III) trichloride
• CAS No.: 7705-07-9
• Molecular Formula: Cl3Ti
• Molecular Weight: 154.239
• Hs Code.: 28273990
• UNII: GVD566MM7K
• Nikkaji Number: J95.274E
• Mol file: 7705-07-9.mol

Synonyms:titanium trichoride;RivastigmineTartrate;titanium (III) chloride;titanium-(III)-chloride;titanium(III) trichloride;LYNX-900;TAC-121;TAS-101;TITANIUM TRICHLORIDE [MI];YONPGGFAJWQGJC-UHFFFAOYSA-K;AKOS015833128

Chemical Property of titanium(III) trichloride

Chemical Property:

• Appearance/Colour: purple crystalline solid
• Melting Point: -24 ºC
• Boiling Point: 100 ºC
• PSA: 0.00000
• Density: 1.2
• LogP: 2.06850
• Sensitive.: Air Sensitive
• Water Solubility.: Soluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 152.854499
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

98% ^*data from raw suppliers

Titanium(III) chloride solution ≥12% TiCl3 basis ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C,F
• Statements: 34-37-35-17-14
• Safety Statements: 6-26-30-36/37/39-43-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Ti+3]
• Uses: It is mainly used as a strong reducing agent; as the catalyst of Α-olefin polymerization. It can be used for azo dye analysis. It can be used as the titrant of azo dye analysis and strong reducing agent. Titanium Chloride (≥12% HCl Solution) is ued in the optimized gas chromatography tandem mass spectrometry for 1,1''-sulfonylbis[2-(methylthio)ethane] quantification in human urine As powerful reducing agent, Titanous chlorideb can reduces nitrate to ammonia; when boiled with aqueous SO2, sulfur is separated; hence is used as an aqueous solution for estimation of nitro groups, ferric ions, per-salts, etc. Removes stains, etc. (stripper) in laundering.
• Physical properties: Red-violet hexagonal crystals; hygroscopic; density 2.64 g/cm3; decomposes on heating above 425°C; also decomposes in water, evolving heat; soluble in alcohol, acetonitrile and certain amines; insoluble in hydrocarbons and ether.

Technology Process of titanium(III) trichloride

There total 48 articles about titanium(III) trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

bis(η6-toluene)titanium(0) (55527-82-7) + titanium tetrachloride (7550-45-0) → titanium(III) chloride (7705-07-9)

Guidance literature:

In n-heptane; byproducts: CH3C6H5; under purified Ar atm.; soln. of TiCl4 in heptane added to soln. of Ti(η6-MeC6H5)2 in heptane; mixt. stirred for 18 h at room temp.; solid filtered; washed (heptane); dried (vac.); elem. anal.;

DOI:10.1016/j.jorganchem.2005.03.064

Reference yield:

triisobutylaluminum (100-99-2,130565-62-7) + titanium tetrachloride (7550-45-0) → (CH2CH(CH3)2)TiCl2 + β-titanium trichloride (7705-07-9) + titanium chloride (10049-06-6) + diisobutylaluminum chloride (1779-25-5)

Guidance literature:

In not given; inert gas atm., Al(iso-C4H9)3/TiCl4 ratio greater than 1 (up to 2); centrifuging or filtration; liq. phase examined by ESR and 1H-NMR;

Reference yield:

titanium tetrachloride (7550-45-0) + magnesium (7439-95-4) → titanium (7440-32-6) + titanium chloride (10049-06-6) + titanium(III) chloride (7705-07-9) + magnesium chloride (7786-30-3)

Guidance literature:

In neat (no solvent); Mg film exposing to TiCl4 at 1E-7 and 1E-6 Torr; monitoring by XPS;

DOI:10.1021/jp982017y

upstream raw materials:

titanium

sodium chloride

titanium tetrachloride

magnesium

Downstream raw materials:

2-amino-4-(2-chloro-6-fluoro-4-trifluoromethylphenoxy)acetanilide

2,3-bis(2-fluoro-4-methoxyphenyl)-2,3-dimethylbutane

(2-amino-5-bromo-phenyl)-(3-chloro-phenyl)-methanone

chlorine

Refernces

• 1、 Fresenius, R.. "". . p. 410 - 412. Retrieved 1885.
• 2、 Pollini. "ELECTRONIC TRANSITIONS IN alpha - AND beta -TITANIUM TRICHLORIDE.". . p. 403 - 408. Retrieved 1983.
• 3、 Mamaeva, G. I.,Romanov, G. V.,Spiridonov, V. P.,Troyanov, S. I.. "DETERMINATION OF STRUCTURES OF MOLECULES OF LOWER HALIDES OF TRANSITION ELEMENTS BY GAS ELECTRON-DIFFRACTION ANALYSIS. I. TITANIUM TRICHLORIDE". . p. 846 - 849. Retrieved 1987.
• 4、 Takeda, Osamu,Okabe, Toru H.. "Fundamental study on synthesis and enrichment of titanium subchloride". . p. 376 - 383. Retrieved 2009/02/01.
• 5、 Calderazzo, Fausto,Englert, Ulli,Pampaloni, Guido,Volpe, Manuel. "Redox reactions with bis(η6-arene) derivatives of early transition metals". . p. 3321 - 3332. Retrieved 2007/10/03.