Titanium(II) chloride

Base Information

• Chemical Name: Titanium(II) chloride
• CAS No.: 10049-06-6
• Molecular Formula: Cl₂Ti
• Molecular Weight: 118.786
• UNII: BK26WI342Q
• Nikkaji Number: J95.275C
• Wikipedia: Titanium(II) chloride,Titanium(II)_chloride
• Mol file: 10049-06-6.mol

Synonyms:Titanium(II) chloride;titanium(2+);dichloride;TITANIUM DICHLORIDE [MI];ZWYDDDAMNQQZHD-UHFFFAOYSA-L

Chemical Property of Titanium(II) chloride

Chemical Property:

• Vapor Pressure: 33900mmHg at 25°C
• Melting Point: 1035oC
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 1.37900
• Water Solubility.: decomposed by H2O evolving H2and forming TiCl3 [KIR83]; soluble alcohol; insoluble chloroform, ether, CS2 [MER06]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 117.885646
• Heavy Atom Count: 3
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Titanium(II) chloride anhydrous, powder, 99.98% trace metals basis ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Flammable, dangerous fire risk, ignites in air, store under water or inert gas.
• Hazard Codes: F,C
• Statements: 14/15-17-34
• Safety Statements: 16-24-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Ti+2]

Technology Process of Titanium(II) chloride

There total 31 articles about Titanium(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triisobutylaluminum (100-99-2,130565-62-7) + titanium tetrachloride (7550-45-0) → (CH2CH(CH3)2)TiCl2 + β-titanium trichloride (7705-07-9) + titanium chloride (10049-06-6) + diisobutylaluminum chloride (1779-25-5)

Guidance literature:

In not given; inert gas atm., Al(iso-C4H9)3/TiCl4 ratio greater than 1 (up to 2); centrifuging or filtration; liq. phase examined by ESR and 1H-NMR;

Reference yield:

titanium tetrachloride (7550-45-0) + magnesium (7439-95-4) → titanium (7440-32-6) + titanium chloride (10049-06-6) + titanium(III) chloride (7705-07-9) + magnesium chloride (7786-30-3)

Guidance literature:

In neat (no solvent); Mg film exposing to TiCl4 at 1E-7 and 1E-6 Torr; monitoring by XPS;

DOI:10.1021/jp982017y

Reference yield:

titanium tetrachloride (7550-45-0) + magnesium (7439-95-4) → titanium chloride (10049-06-6) + magnesium chloride (7786-30-3)

Guidance literature:

In neat (no solvent); reaction of TiCl4 with Mg film on gold; IR, XPS;

DOI:10.1016/j.susc.2005.04.038

upstream raw materials:

sodium chloride

titanium tetrachloride

magnesium

titanium

Downstream raw materials:

titanium(IV)

Refernces

• 1、 Vlaic, G.,Bart, J. C. J.,Cavigiolo, W.,Mobilio, S.,Navara, G.. "". . p. 115 - 122. Retrieved 1982.
• 2、 Pilling,Fonseca, A. Amieiro,Cousins,Waugh,Surman,Gardner. "Combined far infrared RAIRS and XPS studies of TiCl4 adsorption and reaction on Mg films". . p. 78 - 87. Retrieved 2005.
• 3、 Berezovskii,Snigireva. "The heat capacity of titanium di-and tetrachloride over the temperature range 7-314 K". . p. 1656 - 1660. Retrieved 2006.
• 4、 Mobin, M.,Malik, A. U.,Ahmad, Sultan. "High temperature interactions of metal oxides with NaCl". . p. 1 - 14. Retrieved 1990.
• 5、 Polacek, J.,Antropiusova, H.,Petrusova, L.,Mach, K.. "Titanium-catalyzed cyclotrimerization of butadiene. Part II. The (C6H6)TiII(AlCl4)2-EtxAlCl3-x (x=1-3) systems". . p. 53 - 74. Retrieved 1990.