l-Piperitone

Base Information Edit

Chemical Name:l-Piperitone
CAS No.:4573-50-6
Molecular Formula:C10H16O
Molecular Weight:152.236
Hs Code.:2914299000
European Community (EC) Number:224-957-0
UNII:8GZY0Q0N20
DSSTox Substance ID:DTXSID10884090
Nikkaji Number:J297.828H
Wikidata:Q27121390
Metabolomics Workbench ID:47033
ChEMBL ID:CHEMBL2229207
Mol file:4573-50-6.mol

Synonyms:l-piperitone;4573-50-6;(R)-6-(Isopropyl)-3-methylcyclohex-2-en-1-one;Piperitone, L-;(-)-piperitone;(6R)-3-methyl-6-propan-2-ylcyclohex-2-en-1-one;2-Cyclohexen-1-one, 3-methyl-6-(1-methylethyl)-, (6R)-;UNII-8GZY0Q0N20;8GZY0Q0N20;CHEBI:48934;EINECS 224-957-0;(6R)-3-methyl-6-(propan-2-yl)cyclohex-2-en-1-one;(R)-Piperitone;(6R)-6-isopropyl-3-methylcyclohex-2-en-1-one;piperiton;laevo-piperitone;(+/-)-Piperitone;(r)-(-)-piperitone;(6R)-3-methyl-6-(1-methylethyl)-2-cyclohexen-1-one;L-PIPERITONE [FHFI];(-)-p-Menth-1-en-3-one;SCHEMBL3508682;CHEMBL2229207;FEMA NO. 4200;DTXSID10884090;FEMA NO. 2910, L-;MFCD23380212;p-Menth-1-en-3-one, (R)-(-)-;P1783;(-)-6-Isopropyl-3-methyl-2-cyclohexen-1-one;Q27121390;2-Cyclohexen-1-one, 3-methyl-6-(1-methylethyl)-, (R)-

Suppliers and Price of l-Piperitone

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Atlantic Research Chemicals
(-)-Piperitone 95%
5gm:
$ 212.07

Atlantic Research Chemicals
(-)-Piperitone 95%
250mgs:
$ 35.35

AK Scientific
d-Piperitone
5g
$ 587.00

AK Scientific
d-Piperitone
1g
$ 272.00

Total 13 raw suppliers

Chemical Property of l-Piperitone Edit

Chemical Property:

Vapor Pressure:0.0572mmHg at 25°C
Boiling Point:233°C at 760 mmHg
Flash Point:90.9°C
PSA：17.07000
Density:0.915g/cm³
LogP:2.56780
Water Solubility.:2.479g/L at 20℃
XLogP3:2.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:152.120115130
Heavy Atom Count:11
Complexity:189

Purity/Quality:

99.9% ^*data from raw suppliers

(-)-Piperitone 95% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CC(=O)C(CC1)C(C)C
Isomeric SMILES:CC1=CC(=O)[C@H](CC1)C(C)C

Technology Process of l-Piperitone

There total 10 articles about l-Piperitone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 1415503-66-0
2-isopropyl-5-methylcyclohexa-1,5-dien-1-yl 2-chloroacetate

: 4573-50-6
(-)-piperitone

Guidance literature:: With N-9-anthracenylmethylcinchonidinium chloride; potassium hydroxide; 2-chloro-ethanol; In chloroform; 1,3,5-trimethyl-benzene; at -40 ℃; for 24h; Reagent/catalyst; Concentration; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ol3027363

Reference yield: 60.0%

: 10458-14-7,14073-97-3,17627-49-5,7786-64-3
(2R,5S)-menthone

: 4573-50-6,6091-52-7,89-81-6,6091-50-5
(S)-(+)-piperitone

Guidance literature:: (2R,5S)-menthone; With bis(2,2,6,6-tetramethyl-1-piperidyl)zinc; In toluene; at 0 ℃; for 0.166667h; Inert atmosphere;

With bis(η3-allyl-μ-chloropalladium(II)); allyl diethyl phosphate; In toluene; at 0 - 120 ℃; for 0.5h; Inert atmosphere; Sealed tube;
DOI:10.1021/acs.orglett.7b03818

Reference yield: 58.0%

: 142835-88-9
(2S,5R)-6-phenylselenenylmenthone

: 4573-50-6,6091-52-7,89-81-6,6091-50-5
(S)-(+)-piperitone

Guidance literature:: With dihydrogen peroxide; magnesium sulfate; In tetrahydrofuran; for 4h; Ambient temperature;
DOI:10.1016/S0040-4020(01)80539-1