Technology Process of C31H50O6
There total 1 articles about C31H50O6 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
methyl 3α-acetoxy-5β-chol-9(11)-en-24-oate;
With
tert.-butylhydroperoxide; sodium hypochlorite;
In
water; ethyl acetate;
at 0 - 5 ℃;
for 7h;
With
sodium sulfite;
In
ethyl acetate;
With
pyridinium chlorochromate;
In
ethyl acetate;
Product distribution / selectivity;
- Guidance literature:
-
With
tert.-butylhydroperoxide; palladium on activated charcoal; potassium carbonate;
In
dichloromethane;
at 20 ℃;
for 24h;
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: potassium carbonate; hydrogen / palladium on activated charcoal / dichloromethane / 24 h / 20 °C
2.1: hydrogen / palladium 10% on activated carbon / ethyl acetate / 16 h / 45 - 50 °C / 2585.81 Torr
3.1: lithium tri-t-butoxyaluminum hydride / tetrahydrofuran / 5 h / 0 - 10 °C
3.2: 0 - 5 °C
4.1: sodium hydroxide; water / tetrahydrofuran; methanol / 4 h / 25 - 35 °C
4.2: pH 1 - 2
With
water; hydrogen; potassium carbonate; lithium tri-t-butoxyaluminum hydride; sodium hydroxide;
palladium 10% on activated carbon; palladium on activated charcoal;
In
tetrahydrofuran; methanol; dichloromethane; ethyl acetate;