ETHANOL, 2,2'-(PHENYLIMINO)BIS-, DIACETATE (ester)

Base Information

• Chemical Name: ETHANOL, 2,2'-(PHENYLIMINO)BIS-, DIACETATE (ester)
• CAS No.: 19249-34-4
• Molecular Formula: C14H19NO4
• Molecular Weight: 265.309
• Hs Code.: 2922499990
• European Community (EC) Number: 242-918-6
• DSSTox Substance ID: DTXSID8066472
• Nikkaji Number: J31.535D
• Wikidata: Q72462510
• Mol file: 19249-34-4.mol

Synonyms:19249-34-4;N,N-Diacetoxyethylaniline;N-Phenyldiethanolamine diacetate;N,N-Bis(2-acetoxyethyl)aniline;Phenyldiethanolamine diacetate;ETHANOL, 2,2'-(PHENYLIMINO)BIS-, DIACETATE (ester);(Phenylazanediyl)bis(ethane-2,1-diyl) diacetate;2-[N-(2-acetyloxyethyl)anilino]ethyl acetate;2,2'-(Phenylimino)bisethyl diacetate;2,2'-Phenyliminodiethanol diacetate;EINECS 242-918-6;BRN 2868361;Ethanol, 2,2'-(phenylimino)bis-, 1,1'-diacetate;2,2'-(Phenylimino)bis(ethanol) diacetate;2,2'-(Phenylimino)diethanol diacetate (ester);N,N-bis-(2-acetoxy-ethyl)-aniline;4-12-00-00286 (Beilstein Handbook Reference);n,n-Diacetoxyethyl aniline;(Phenylazanediyl)bis(ethane-2,1-diyl)diacetate;N,N-Bisacetoxyethyl aniline;SCHEMBL3395917;DTXSID8066472;N,N-di(2-acetyloxyethyl)aniline;N,N-Di-(2-acetoxyethyl)aniline;AKOS015960715;2,2/'-(Phenylimino)bisethyl diacetate;N,N-Bis(2-acetoxyethyl)aniline, 97%;LS-67020;FT-0629604;Diacetic acid 2,2'-(phenylimino)bis(ethyl) ester;W-107718

Chemical Property of ETHANOL, 2,2'-(PHENYLIMINO)BIS-, DIACETATE (ester)

Chemical Property:

• Vapor Pressure: 9.7E-06mmHg at 25°C
• Refractive Index: n20/D 1.523(lit.)
• Boiling Point: 372.32 °C at 760 mmHg
• PKA: 4.79±0.50(Predicted)
• Flash Point: 178.973 °C
• PSA: 55.84000
• Density: 1.137 g/cm³
• LogP: 1.61920
• XLogP3: 1.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 9
• Exact Mass: 265.13140809
• Heavy Atom Count: 19
• Complexity: 267

Purity/Quality:

99% ^*data from raw suppliers

(Phenylazanediyl)bis(ethane-2,1-diyl)diacetate 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 22-41
• Safety Statements: 26-36/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=O)OCCN(CCOC(=O)C)C1=CC=CC=C1

Technology Process of ETHANOL, 2,2'-(PHENYLIMINO)BIS-, DIACETATE (ester)

There total 6 articles about ETHANOL, 2,2'-(PHENYLIMINO)BIS-, DIACETATE (ester) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

2,2'-(phenylimino)bis[ethanol] (120-07-0) + acetyl chloride (75-36-5) → bis(2-acetoxyethyl)aniline (19249-34-4)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 35 ℃; for 15h;

DOI:10.1016/s0040-4039(98)01499-3

Reference yield: 93.0%

2,2'-(phenylimino)bis[ethanol] (120-07-0) + acetic anhydride (108-24-7) → bis(2-acetoxyethyl)aniline (19249-34-4)

Guidance literature:

With pyridine; for 2h; Heating;

DOI:10.1039/a904945b

Reference yield:

aniline (62-53-3) → bis(2-acetoxyethyl)aniline (19249-34-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 87 percent / 96percent NaOH / 72 h / 100 °C

2: 83 percent / pyridine / CH₂Cl₂ / 24 h / Heating

With pyridine; sodium hydroxide; In dichloromethane;

DOI:10.1080/10587259408039194

upstream raw materials:

2,2'-(phenylimino)bis[ethanol]

acetic anhydride

acetic acid

acetyl chloride

Downstream raw materials:

4-(bis(2-acetoxyethyl)amino)benzaldehyde

4-[N,N-bis(2-acetoxyethyl)amino]phenylacetylene

C₂₁H₂₀Cl₂N₄O₄S

C₁₈H₁₉N₅O₈S

Refernces

• 1、 -. "Double-cyano stilbene ethylene two-photon fluorescent solvent chromophore water-soluble probe and its synthetic method and application (by machine translation)". Paragraph 0037-0041. . Retrieved 2018/10/19.
• 2、 -. "Synthetic technology of hydroxyethylaniline ester (III)". Paragraph 0044; 0045. . Retrieved 2016/11/02.