4-(BIS(2-(ACETYLOXY)ETHYL)AMINO)BENZ-

Base Information

• Chemical Name: 4-(BIS(2-(ACETYLOXY)ETHYL)AMINO)BENZ-
• CAS No.: 41313-77-3
• Molecular Formula: C15H19NO5
• Molecular Weight: 293.32
• Hs Code.: 2922509090
• Mol file: 41313-77-3.mol

Synonyms:Benzaldehyde,p-[bis(2-hydroxyethyl)amino]-, diacetate (6CI);4-Formyldiacetyl-N-phenyldiethanolamine;4-[Bis(2-acetoxyethyl)amino]benzaldehyde;4-[N,N-Bis(2-acetoxyethyl)amino]benzaldehyde;4-[N,N-Bis(2-acetyloxyethyl)amino]benzaldehyde;NSC 308801;O,O'-Diacetyl-4-formyl-N-phenyldiethanolamine;p-Bis(2-acetoxyethyl)aminobenzaldehyde;

Chemical Property of 4-(BIS(2-(ACETYLOXY)ETHYL)AMINO)BENZ-

Chemical Property:

• Vapor Pressure: 1.59E-07mmHg at 25°C
• Melting Point: 60-63 °C(lit.)
• Refractive Index: 1.554
• Boiling Point: 427.8 °C at 760 mmHg
• Flash Point: 212.5 °C
• PSA: 72.91000
• Density: 1.196 g/cm³
• LogP: 1.43170

Purity/Quality:

99% ^*data from raw suppliers

4-[Bis[2-(acetyloxy)ethyl]amino]benzaldehyde 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of 4-(BIS(2-(ACETYLOXY)ETHYL)AMINO)BENZ-

There total 6 articles about 4-(BIS(2-(ACETYLOXY)ETHYL)AMINO)BENZ- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

bis(2-acetoxyethyl)aniline (19249-34-4) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → 4-(bis(2-acetoxyethyl)amino)benzaldehyde (41313-77-3)

Guidance literature:

With trichlorophosphate; at 0 - 90 ℃; for 2.5h;

Reference yield: 92.0%

acetic anhydride (108-24-7) + 4-(bis(2-hydroxyethyl)amino)benzaldehyde (27913-86-6) → 4-(bis(2-acetoxyethyl)amino)benzaldehyde (41313-77-3)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In tetrahydrofuran; at 20 ℃; for 24h;

DOI:10.1021/jo052542a

Reference yield: 73.0%

4-(bis(2-hydroxyethyl)amino)benzaldehyde (27913-86-6) + acetyl chloride (75-36-5) → 4-(bis(2-acetoxyethyl)amino)benzaldehyde (41313-77-3)

Guidance literature:

With triethylamine; In dichloromethane; at 20 ℃; for 6h;

DOI:10.1248/cpb.55.1740

upstream raw materials:

bis(2-acetoxyethyl)aniline

N,N-dimethyl-formamide

acetic anhydride

4-(bis(2-hydroxyethyl)amino)benzaldehyde

Downstream raw materials:

2-{[4-Bis(acetoxyethyl)phenyl]ethenyl}-3,5-dinitrothiophene

C₃₃H₂₉NO₁₀

4-N,N-di[2-(p-benzoylphenylmethoxy)ethyl]amino-4'-nitrostilbene

3,4-bis(hexyloxy)-2-{4-[N,N-di[2-(acetyloxy)ethyl]amino]styryl}thiophene

Refernces

• 1、 Kandinska, Meglena I.,Kitova, Snejana M.,Videva, Vladimira S.,Stoyanov, Stanimir S.,Yordanova, Stanislava B.,Baluschev, Stanislav B.,Angelova, Silvia E.,Vasilev, Aleksey A.. "Precious metal-free molecular machines for solar thermal energy storage". supporting information. p. 1096 - 1106. Retrieved 2019/06/08.
• 2、 Wu, Chia-Shing,Lin, Ying-Ju,Chen, Yun. "A fluorene-based material containing triple azacrown ether groups: Synthesis, characterization and application in chemosensors and electroluminescent devices". . p. 1419 - 1429. Retrieved 2014/03/21.