iron(3+) acetate

Base Information

• Chemical Name: iron(3+) acetate
• CAS No.: 1834-30-6
• Molecular Formula: 2C₂H₃O₂*Fe
• Molecular Weight: 173.936
• Mol file: 1834-30-6.mol

Synonyms:Aceticacid, iron(3+) salt (8CI,9CI);Ferric acetate;Iron triacetate;Iron(3+) triacetate;Iron acetate;AC1L4VO7;Acetic acid, iron(3+) salt;AR-1J0754;

Chemical Property of iron(3+) acetate

Chemical Property:

• Boiling Point: 117.1 °C at 760 mmHg
• Flash Point: 40 °C
• PSA: 120.39000
• LogP: -3.73390

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of iron(3+) acetate

There total 22 articles about iron(3+) acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

acetic anhydride (108-24-7) + iron (7439-89-6) + acetic acid (64-19-7,77671-22-8) → iron(II) acetate (1834-30-6,2140-52-5,3094-87-9)

Guidance literature:

In acetic anhydride; acetic acid; byproducts: H2; Schlenk technique, under Ar; acetic acid and acetic anhydride heated to reflux, reacted with Fe (54 mmol) at boiling for 4 h; B. Heyn et al., Anorganische Syntesechemie, V.2, Springer, Heildeberg, 1986; ppt. filtered off, washed with Et2O, dried in vac.; elem. anal.;

DOI:10.1002/zaac.201000274

Reference yield: 77.0%

iron pentacarbonyl (13463-40-6,37220-42-1) → iron(II) acetate (1834-30-6,2140-52-5,3094-87-9)

Guidance literature:

With acetic acid; acetic anhydride; In N,N-dimethyl-formamide; N2-atmosphere; filtration of Fe(CO)5 into soln. of HOAc and acetic anhydride, heating to 80°C, then to 115 -120°C 60 h; crystn., filtration, washing (benzene), drying (vac., over H2SO4 and CaCl2); elem. anal.;

DOI:10.1039/DT9770001420

Reference yield: 65.0%

iron (7439-89-6) + acetic acid (64-19-7,77671-22-8) → iron(II) acetate (1834-30-6,2140-52-5,3094-87-9)

Guidance literature:

With hydrogenchloride; In water; at 20 ℃; for 2h; Inert atmosphere; Schlenk technique;

DOI:10.1002/chem.201803501

upstream raw materials:

iron

Sucrose

acetic acid

acetic anhydride

Downstream raw materials:

5,10,15,20-tetraphenyl porphyrinato iron hydroxide

Fe(5,10,15,20-tetraphenylporphine)CO(4-acetoxypyridine)

Refernces

• 1、 Catterick, Janet,Thornton, Peter,Fitzsimmons, Brian W.. "". . . Retrieved 1977.
• 2、 Pai, Sandesh,Schott, Marco,Niklaus, Lukas,Posset, Uwe,Kurth, Dirk G.. "A study of the effect of pyridine linkers on the viscosity and electrochromic properties of metallo-supramolecular coordination polymers". . p. 3310 - 3321. Retrieved 2018.
• 3、 Weber, Birgit,Betz, Richard,Bauer, Wolfgang,Schlamp, Stephan. "Crystal structure of iron(II) acetate". . p. 102 - 107. Retrieved 2011.
• 4、 Bhosale,Choudhari,Sawant,Patil,Kulkarni,Kelkar. "Thermoanalytical study of Cu-Mg-Zn ferrites". . p. 851 - 859. Retrieved 1999.
• 5、 Kra?unovska,T?pfer. "On the thermal stability of Co2Z hexagonal ferrites for low-temperature ceramic cofiring technologies". . p. 1370 - 1376. Retrieved 2008.
• 6、 Wang, Yuanyuan,Ang, Pau Lin,Wong, Chun-Yuen,Yip, John H. K.. "Gold-Clip-Assisted Self-Assembly and Proton-Coupled Expansion–Contraction of a Cofacial FeIII–Porphyrin Cage". . p. 18623 - 18628. Retrieved 2018.
• 7、 Munzert, Stefanie Martina,Stier, Simon P.,Schwarz, Guntram,Weissman, Haim,Rybtchinski, Boris,Kurth, Dirk G.. "The Kinetics of Growth of Metallo-supramolecular Polyelectrolytes in Solution". . p. 2898 - 2912. Retrieved 2017/10/06.