5,10,15,20-tetraphenyl porphyrinato iron hydroxide

Base Information

• Chemical Name: 5,10,15,20-tetraphenyl porphyrinato iron hydroxide
• CAS No.: 25482-26-2
• Molecular Formula: C₄₄H₂₉FeN₄O
• Molecular Weight: 685.587
• Mol file: 25482-26-2.mol

Synonyms:5,10,15,20-tetraphenyl porphyrinato iron hydroxide

Chemical Property of 5,10,15,20-tetraphenyl porphyrinato iron hydroxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15,20-tetraphenyl porphyrinato iron hydroxide

There total 8 articles about 5,10,15,20-tetraphenyl porphyrinato iron hydroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

5,10,15,20-tetraphenyl porphyrin iron (16591-56-3) → 5,10,15,20-tetraphenyl porphyrinato iron hydroxide (25482-26-2)

Guidance literature:

With O₂; In dichloromethane; Fe(II) porphyrin dissolved in CH2Cl2, O2 added in the presence of Na2S2O3 and CF3CO2H; elem. anal.;

DOI:10.1246/bcsj.73.1153

Reference yield:

Fe(tetraphenylporphyrinato)(1-methylimidazole)2(1+) (52155-25-6) + tetra-n-butylammonium hydroxide → 5,10,15,20-tetraphenyl porphyrinato iron hydroxide (25482-26-2)

Guidance literature:

In dichloromethane;

DOI:10.1021/ja00373a042

Reference yield:

chloro[5,10,15,20-tetraphenylporphyrinato]iron(III) → 5,10,15,20-tetraphenyl porphyrinato iron hydroxide (25482-26-2)

Guidance literature:

With hydroxide; In pyridine; addition of OH(1-) to soln. of complex in pure pyridine; UV, cyclic voltammetry;

upstream raw materials:

iron(III) tetraphenylporphyrin

meso-tetraphenylporphyrin iron(III) chloride

Fe(tetraphenylporphyrinato)(1-methylimidazole)2⁽¹⁺⁾

sodium hydroxide

Downstream raw materials:

azido(tetraphenylporphyrinato)iron(III)

Refernces

• 1、 Oyaizu, Kenichi,Haryono, Agus,Natori, Junichiro,Shinoda, Hiroshi,Tsuchida, Eishun. "Electroreduction of μ-oxo iron(III) porphyrins adsorbed on an electrode leading to a cofacial geometry for the iron(II) complex: Unexpected active site for the catalytic reduction of O2 to H2O". . p. 1153 - 1163. Retrieved 2007/10/03.
• 2、 Miksztal, Andrew R.,Valentine, Joan Selverstone. "Reactivity of the peroxo ligand in metalloporphyrin complexes. Reaction of sulfur dioxide with iron and titanium porphyrin peroxo complexes to give sulfato complexes or sulfate". . p. 3548 - 3552. Retrieved 2008/10/08.