Iron(III) diethyldithiocarbamate

Base Information

• Chemical Name: Iron(III) diethyldithiocarbamate
• CAS No.: 13963-59-2
• Molecular Formula: C15H30 Fe N3 S6
• Molecular Weight: 500.666
• Mol file: 13963-59-2.mol

Synonyms:Diethyldithiocarbamic Acid Ferric Salt;Iron diethyldithiocarbamate;Diethyldithiocarbamic Acid Iron(III) Salt;iron(iii) diethyl-dithiocarbamate;tris(diethylcarbamothioylthio)iron;MFCD00070507;AKOS025311049;Diethyldithiocarbamic acid iron(iii)salt;D89665

Chemical Property of Iron(III) diethyldithiocarbamate

Chemical Property:

• Boiling Point: 176.4°Cat760mmHg
• Flash Point: 60.5°C
• PSA: 181.89000
• Density: g/cm³
• LogP: 5.42930
• Solubility.: slightly sol. in Chloroform
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 6
• Exact Mass: 500.011336
• Heavy Atom Count: 25
• Complexity: 294

Purity/Quality:

99% ^*data from raw suppliers

Iron(III) Diethyldithiocarbamate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Moderately toxic.
• Hazard Codes: Moderately toxic.

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCN(CC)C(=S)[S-].CCN(CC)C(=S)[S-].CCN(CC)C(=S)[S-].[Fe+3]
• Uses: Iron(III) Diethyldithiocarbamate is an organometallic complex used as a catalyst in the decomposition of tertiary hydroperoxides.

Technology Process of Iron(III) diethyldithiocarbamate

There total 4 articles about Iron(III) diethyldithiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iron(III) chloride hexahydrate (121714-78-1,24290-40-2,58694-80-7,10025-77-1,64333-00-2) + sodium N,N-diethyldithiocarbamate (148-18-5) → tris(N,N-diethyldithiocarbamato)iron(III) (13963-59-2)

Guidance literature:

In ethanol; byproducts: NaCl; stoich. amts. of FeCl3*6H2O and Na diethyldithiocarbamate in EtOH; filtered; ppt. washed with water and EtOH; dried at room temp.;

DOI:10.1021/ic049049m

Reference yield:

disulfiram (97-77-8) + iron (7439-89-6) → tris(N,N-diethyldithiocarbamato)iron(III) (13963-59-2)

Guidance literature:

In acetone; Electrolysis; 2 h, initial voltage 25 V, Fe anode; product was collected, washed with acetonitrile and then petroleum ether and dried in vacuo; elem. anal.;

Reference yield:

iron(III) chloride hexahydrate + sodium N,N-diethyldithiocarbamate (148-18-5) → tris(N,N-diethyldithiocarbamato)iron(III) (13963-59-2)

Guidance literature:

In methanol;

DOI:10.1021/cm5030553

upstream raw materials:

Ditiocarb ammonium

iron(III) chloride hexahydrate

sodium N,N-diethyldithiocarbamate

disulfiram

Downstream raw materials:

bis(N,N-diethyldithiocarbamato)mercury(II)

Refernces

• 1、 Yoder, Tara S.,Cloud, Jacqueline E.,Leong, G. Jeremy,Molk, Doreen F.,Tussing, Matthew,Miorelli, Jonathan,Ngo, Chilan,Kodambaka, Suneel,Eberhart, Mark E.,Richards, Ryan M.,Yang, Yongan. "Iron pyrite nanocrystal inks: Solvothermal synthesis, digestive ripening, and reaction mechanism". . p. 6741 - 6751. Retrieved 2014.
• 2、 Geloso, Corrado,Kumar, Rajesh,Lopez-Grado, Jaime Romero,Tuck, Dennis G.. "THE DIRECT ELECTROCHEMICAL SYNTHESIS OF DIALKYLDITHIOCARBAMATE AND DIETHYLDITHIOPHOSPHATE COMPLEXES OF MAIN GROUP AND TRANSITION METALS". . p. 928 - 932. Retrieved 2007/10/02.