PHENYLMERCURIC IODIDE

Base Information

• Chemical Name: PHENYLMERCURIC IODIDE
• CAS No.: 823-04-1
• Molecular Formula: C6H5 Hg I
• Molecular Weight: 404.6
• Mol file: 823-04-1.mol

Synonyms:Mercury,phenyl-, iodide (5CI); Phenylmercury iodide (6CI); Iodomercuribenzene;Iodophenylmercury; PMI; Phenyliodomercury; Phenylmercuric iodide

Chemical Property of PHENYLMERCURIC IODIDE

Chemical Property:

Purity/Quality:

98%min ^*data from raw suppliers

PHENYLMERCURIC IODIDE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of PHENYLMERCURIC IODIDE

There total 23 articles about PHENYLMERCURIC IODIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

mercury(II) iodide + bis(iodomethyl)mercury (4819-11-8) + diphenylmercury(II) (587-85-9,1337-09-3) → phenylmercuric iodide (823-04-1)

Guidance literature:

With cis-Cyclooctene; In further solvent(s); undecane as solvent, 34h at 85°C, under N2 or Ar; cooled;

Reference yield: 85.0%

(Iodomethyl)mercuric iodide (141-51-5) + diphenylmercury(II) (587-85-9,1337-09-3) → phenylmercuric iodide (823-04-1)

Guidance literature:

With cis-Cyclooctene; In further solvent(s); undecane as solvent, 30h, 85°C, under N2 or Ar; colled, filtered;

Reference yield: 81.0%

C5(CH3)5(1-)*Ir(3+)*(CH3)2SO*2I(1-)=[(C5(CH3)5)Ir(I2)((CH3)2SO)] + diphenylmercury(II) (587-85-9,1337-09-3) → (C5(CH3)5)Ir(CO)I(C6H5) + phenylmercuric iodide (823-04-1)

Guidance literature:

With CO; In dichloromethane; N2, Schlenk techniques; Hg-compd. addn. to Ir-compd. soln., stirring (20 h, room temp.), ppt. filtration off, solvent removal (vac.), solid dissoln., filtration, solvent removal, residue redissoln., CO bubbling through soln. (5 h, room temp.); solvent removal (vac.), residue chromy. (alumina, Et2O/CH2Cl2 9:1 eluent), solvent removal, residue washing (pentane), drying; elem. anal.;

DOI:10.1016/0020-1693(95)04573-2

upstream raw materials:

phenylboronic acid

diphenylmercury(II)

1-phenyl-2,8,9-trioxa-5-aza-1-silabicyclo{3.3.3}undecane

iodine

Downstream raw materials:

Hg(C₆H₅)(SC₆F₅)

biphenyl

1-phenyl-4-nitrobenzene

4-chlorobenzophenone

Refernces

• 1、 Voronkov, M. G.,Chermov, N. F.,Perlova, E. M.. "Nucleophilic cleavage of the Si-C bond in organotrifluorosilanes and diorganodifluorosilanes". . p. 225 - 230. Retrieved 2007/10/02.
• 2、 Nies, J. Dirk,Bellama, Jon M.,Ben-Zvi, Nava. "DIRECT TRANSFER OF ALIPHATIC AND AROMATIC SUBSTITUENTS FROM ORGANOSILATRANES TO MERCURY(II) SPECIES". . p. 315 - 320. Retrieved 2007/10/02.