1,2,3,4-Tetrachlorobutane

Base Information

• Chemical Name: 1,2,3,4-Tetrachlorobutane
• CAS No.: 3405-32-1
• Molecular Formula: C4H6 Cl4
• Molecular Weight: 195.904
• Hs Code.: 2903199000
• European Community (EC) Number: 222-287-3
• NSC Number: 227860
• DSSTox Substance ID: DTXSID90951198
• Nikkaji Number: J45.859G
• Mol file: 3405-32-1.mol

Synonyms:1,2,3,4-TETRACHLOROBUTANE;3405-32-1;Butane, 1,2,3,4-tetrachloro-;EINECS 222-287-3;NSC 227860;AI3-08519;EINECS 249-059-6;NSC227860;1,3,4-Tetrachlorobutane;C(Cl)(CCl)C(Cl)CCl;C4H6Cl4;Butane,2,3,4-tetrachloro-;SCHEMBL1536260;DTXSID90951198;CHEBI:143857;AKOS006282583;NSC-227860;LS-45997

Chemical Property of 1,2,3,4-Tetrachlorobutane

Chemical Property:

• Melting Point: 28.17°C (estimate)
• Refractive Index: 1.4865 (estimate)
• Boiling Point: 191.03°C (estimate)
• PSA: 0.00000
• Density: 1.3920 (estimate)
• LogP: 2.67880
• XLogP3: 2.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 195.919411
• Heavy Atom Count: 8
• Complexity: 48

Purity/Quality:

99%, ^*data from raw suppliers

1,2,3,4-TETRACHLOROBUTANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(C(CCl)Cl)Cl)Cl

Technology Process of 1,2,3,4-Tetrachlorobutane

There total 28 articles about 1,2,3,4-Tetrachlorobutane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-1,4-dichlorobut-2-ene (110-57-6) → meso-1,2,3,4-tetrachlorobutane (28507-96-2) + racem.-1,2,3,4-Tetrachlorbutan (3405-32-1,28507-96-2,52134-24-4) + (2S,3S)-1,2,4-Trichloro-3-methoxy-butane (76465-31-1,76465-32-2,76951-33-2,76951-34-3) + (2S,3R)-1,2,4-Trichloro-3-methoxy-butane (76465-31-1,76465-32-2,76951-33-2,76951-34-3)

Guidance literature:

With chlorine; In dichloromethane; at -20 ℃; Further byproducts given;

Reference yield:

methanol (67-56-1) + 3,4-dichlorobut-1-ene (310447-99-5,310448-01-2,64037-54-3) → meso-1,2,3,4-tetrachlorobutane (28507-96-2) + racem.-1,2,3,4-Tetrachlorbutan (3405-32-1,28507-96-2,52134-24-4) + (2R,3R)-1,2,3-Trichloro-4-methoxy-butane (76465-33-3,76465-34-4,76951-37-6,76951-38-7) + (2R,3S)-1,2,3-Trichloro-4-methoxy-butane (76465-33-3,76465-34-4,76951-37-6,76951-38-7)

Guidance literature:

With chlorine; at -20 ℃; Further byproducts given;

Reference yield:

methanol (67-56-1) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) → meso-1,2,3,4-tetrachlorobutane (28507-96-2) + racem.-1,2,3,4-Tetrachlorbutan (3405-32-1,28507-96-2,52134-24-4) + (2S,3S)-1,2,4-Trichloro-3-methoxy-butane (76465-31-1,76465-32-2,76951-33-2,76951-34-3) + (2R,3S)-1,2,3-Trichloro-4-methoxy-butane (76465-33-3,76465-34-4,76951-37-6,76951-38-7)

Guidance literature:

In dichloromethane; at -20 ℃; Further byproducts given;

upstream raw materials:

1,4-dichloro-2-butene

meso-erythritol

2,3-dimethylbutene

3,4-dichlorobut-1-ene

Downstream raw materials:

2,3-dichlorobuta-1,3-diene

buta-1,3-diene

perfluoro-1,2,3,4-tetrachlorobutane

Refernces

• 1、 -. "Production method and production system of 1,2,3,4-tetrachlorobutane". Paragraph 0018-0033. . Retrieved 2018/12/01.
• 2、 -. "PRODUCTION PROCESS AND PURIFICATION PROCESS FOR 1,2,3,4-TETRACHLOROHEXAFLUOROBUTANE". Page/Page column 6. . Retrieved 2011/04/18.