(1,1′-bis(diphenylphosphino)ferrocene)₂Ni

Base Information

• Chemical Name: (1,1′-bis(diphenylphosphino)ferrocene)₂Ni
• CAS No.: 94202-32-1
• Molecular Formula: C₆₈H₅₆Fe₂NiP₄
• Molecular Weight: 1167.47
• Mol file: 94202-32-1.mol

Synonyms:(1,1′-bis(diphenylphosphino)ferrocene)₂Ni

Chemical Property of (1,1′-bis(diphenylphosphino)ferrocene)₂Ni

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (1,1′-bis(diphenylphosphino)ferrocene)₂Ni

There total 8 articles about (1,1′-bis(diphenylphosphino)ferrocene)₂Ni which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

1,1'-bis-(diphenylphosphino)ferrocene (12150-46-8) + [1,1'-bis(diphenylphosphino)ferrocene]nickel(II) chloride (67292-34-6) → (1,1′-bis(diphenylphosphino)ferrocene)2Ni (94202-32-1)

Guidance literature:

With sodium naphthalenide; In tetrahydrofuran; toluene; (N2); a soln. of sodium naphthalenide in THF added dropwise to a suspn. of Fe complexes in toluene, stirred at room temp. for 30 min; evapd., dissolved in C6H6, filtered, pptd. (hexane), filtered, washed (hexane), dried (vac.); elem. anal.;

DOI:10.1021/ic061185z

Reference yield: 48.0%

(1,1′-bis(diphenylphosphino)ferrocene)Ni(I)Cl + 2,6-dimethylbenzene boronic acid (100379-00-8) → (1,1′-bis(diphenylphosphino)ferrocene)2Ni (94202-32-1)

Guidance literature:

With potassium phosphate; In benzene-d6; at 20 ℃; for 24h;

DOI:10.1021/acscatal.8b00546

Reference yield: 31.0%

(1,1′-bis(diphenylphosphino)ferrocene)Ni(I)Cl + mesitylboronic acid (5980-97-2) → (1,1′-bis(diphenylphosphino)ferrocene)2Ni (94202-32-1) + C43H39FeNiP2

Guidance literature:

With potassium phosphate; In benzene-d6; at 20 ℃; for 24h;

DOI:10.1021/acscatal.8b00546

upstream raw materials:

1,1'-bis-(diphenylphosphino)ferrocene

[1,1'-bis(diphenylphosphino)ferrocene]nickel(II) chloride

bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

(1,1′-bis(diphenylphosphino)ferrocene)Ni(η²-ethylene)

Downstream raw materials:

ferrocene

Refernces

• 1、 Langer, Jens,Fischer, Reinald,Goerls, Helmar,Walther, Dirk. "Low-valent nickel and palladium complexes with 1,1′-bis(phosphanyl)- ferrocenes: Syntheses and structures of acrylic acid and ethylene complexes". . p. 2257 - 2264. Retrieved 2007.
• 2、 Kampmann, Sven S.,Sobolev, Alexandre N.,Koutsantonis, George A.,Stewart, Scott G.. "Stable nickel(0) phosphites as catalysts for C-N cross-coupling reactions". supporting information. p. 1967 - 1973. Retrieved 2014/07/07.