Technology Process of bromodiethylaminophenylphosphine(pentacarbonyl)tungsten(0)
There total 1 articles about bromodiethylaminophenylphosphine(pentacarbonyl)tungsten(0) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
hydrogen bromide;
In
pentane;
Under stirring a strong stream of hydrogenhalogenide is bubbled for 3-10 min through the cooled (-50-0°C) soln. of phosphine complex (inert atmosphere).; Solvent is evapd. at room temp. in vac., residue is digested with pentane, dialkylamminhydrohalogenide is filtered off, filtrate is dried to dryness in vac., recrystn. from pentane (-78°C), not purely isolated.;
DOI:10.1016/0022-328X(89)85002-8
