9-Anthracenecarboxaldehyde, oxime

Base Information

• Chemical Name: 9-Anthracenecarboxaldehyde, oxime
• CAS No.: 34810-13-4
• Molecular Formula: C15H11NO
• Molecular Weight: 221.258
• Hs Code.: 2924299090
• European Community (EC) Number: 625-998-0
• NSC Number: 26820
• Nikkaji Number: J80.506H
• Mol file: 34810-13-4.mol

Synonyms:9-anthramide

Chemical Property of 9-Anthracenecarboxaldehyde, oxime

Chemical Property:

• Vapor Pressure: 5.76E-08mmHg at 25°C
• Melting Point: 162-164 °C(lit.)
• Refractive Index: 1.631
• Boiling Point: 424.571 °C at 760 mmHg
• Flash Point: 275.582 °C
• PSA: 32.59000
• Density: 1.161 g/cm³
• LogP: 3.80110
• XLogP3: 4.3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 221.084063974
• Heavy Atom Count: 17
• Complexity: 267

Purity/Quality:

99% ^*data from raw suppliers

9-Anthraldoxime ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=C3C=CC=CC3=C2C=NO
• Isomeric SMILES: C1=CC=C2C(=C1)C=C3C=CC=CC3=C2/C=N/O
• Uses: 9-Anthraldehyde oxime was used in preparation of new triosmium cluster [Os3(CO)11(C14H9CN)].

Technology Process of 9-Anthracenecarboxaldehyde, oxime

There total 9 articles about 9-Anthracenecarboxaldehyde, oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

9-(aminomethyl)anthracene (2476-68-8) → 9-Anthracene carboxamide (34810-13-4)

Guidance literature:

With C₃₁H₂₉Br₂N₃Ru; potassium tert-butylate; In tert-butyl alcohol; at 70 ℃; for 24h;

DOI:10.1039/d1cy01541a

Reference yield: 85.0%

9-anthracenealdehyde oxime (18004-57-4) → 9-Anthracene carboxamide (34810-13-4)

Guidance literature:

With [RuCl₂(η²-C₆H₆){P(NMe₂)₃}]; water; at 100 ℃; for 7h; Inert atmosphere; Sealed tube;

DOI:10.1021/om3006917

Reference yield: 75.0%

9-anthracene aldehyde (642-31-9) → 9-Anthracene carboxamide (34810-13-4)

Guidance literature:

With hydroxylamine hydrochloride; caesium carbonate; In acetonitrile; at 60 - 65 ℃;

DOI:10.1016/j.tetlet.2012.03.051

upstream raw materials:

Anthracen-carbonsaeure-⁽⁹⁾-amid-N-sulfochlorid

9-cyanoanthracene

anthracene

9-anthracene aldehyde

Downstream raw materials:

anthracen-9-carboxylic acid

9,10-phenanthrenequinone

9-cyanoanthracene

Refernces

• 1、 Sun, Yajun,Jin, Weiwei,Liu, Chenjiang. "Trash to treasure: Eco-friendly and practical synthesis of amides by nitriles hydrolysis in WepPA". supporting information. . Retrieved 2019/11/11.
• 2、 Singh, Kuldeep,Sarbajna, Abir,Dutta, Indranil,Pandey, Pragati,Bera, Jitendra K.. "Hemilability-Driven Water Activation: A NiII Catalyst for Base-Free Hydration of Nitriles to Amides". . p. 7761 - 7771. Retrieved 2017/06/06.