Dibromophenylarsine

Base Information

• Chemical Name: Dibromophenylarsine
• CAS No.: 696-24-2
• Molecular Formula: C6H5 As Br2
• Molecular Weight: 311.835
• DSSTox Substance ID: DTXSID90219866
• Nikkaji Number: J35.216K
• Wikidata: Q83096898
• Mol file: 696-24-2.mol

Synonyms:Dibromophenylarsine;Phenyldibromoarsine;Arsonous dibromide, phenyl-;ARSINE, DIBROMOPHENYL-;Phenylarsonous dibromide;BRN 2935647;696-24-2;Phenylarsine dibromide;C6H5AsBr2;Phenylarsonous dibromide #;C6-H5-As-Br2;SCHEMBL11575710;DTXSID90219866;LS-21822

Chemical Property of Dibromophenylarsine

Chemical Property:

• Vapor Pressure: 0.0157mmHg at 25°C
• Boiling Point: 264.6°C at 760 mmHg
• Flash Point: 112.8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 311.79535
• Heavy Atom Count: 9
• Complexity: 79.1

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[As](Br)Br

Technology Process of Dibromophenylarsine

There total 10 articles about Dibromophenylarsine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.3%

phenylarsonic acid (98-05-5) → Phenyldibromoarsine (696-24-2)

Guidance literature:

With sulfur dioxide; hydrogen bromide;

Reference yield:

dibromo-dimethyl-phenyl-arsorane; compound with bromine → methyl bromide (74-83-9) + Phenyldibromoarsine (696-24-2)

Guidance literature:

at 160 ℃;

Reference yield:

1-phenyl-3,4-dimethyl-3-arsolene (73411-22-0) → cis-1,4-dibromo-2,3-dimethyl-2-butene (100758-26-7) + (E)-1,4-dibromo-2,3-dimethylbut-2-ene (6044-73-1) + Phenyldibromoarsine (696-24-2)

Guidance literature:

With bromine; In chloroform; at -15 ℃;

DOI:10.1016/0022-328X(94)88008-5

upstream raw materials:

phenylarsine oxide

bromo(phenyl)mercury

phenylarsonodithious acid bis-(2-hydroxy-ethyl) ester

phenyl-arsonodithious acid diethyl ester

Downstream raw materials:

3-phenyl-1,2-dicarba-3-arsa-closo-dodecaborane⁽¹²⁾

C₁₀H₁₅AsBrN

bromobenzene

Refernces

• 1、 Khalitov, F. G.,Chadaeva, N. A.,Avvakumova, L. V.. "DIPOLE MOMENTS AND SPATIAL STRUCTURE OF ARYLDIBROMOARSINES". . p. 1832 - 1835. Retrieved 2007/10/02.