D-Pinitol

Base Information

• Chemical Name: D-Pinitol
• CAS No.: 10284-63-6
• Molecular Formula: C7H14O6
• Molecular Weight: 194.185
• Hs Code.: 2906.13
• Mol file: 10284-63-6.mol

Synonyms:Inositol,3-O-methyl-, D-chiro- (8CI);Pinitol, (+)- (6CI,7CI);(+)-Pinitol;3-O-Methyl-(+)-chiro-inositol;3-O-Methyl-D-chiro-inositol;D-(+)-Pinitol;D-3-O-Methyl-chiro-inositol;Inzitol;Matezit;Pinit;Pinite(inositol derivative);Pinitol B;Sennit;Sennitol;

Chemical Property of D-Pinitol

Chemical Property:

• Appearance/Colour: white powder
• Vapor Pressure: 0mmHg at 25°C
• Melting Point: 179-185 °C
• Refractive Index: 1.588
• Boiling Point: 317.2 °C at 760 mmHg
• PKA: 12.98±0.70(Predicted)
• Flash Point: 145.6 °C
• PSA: 110.38000
• Density: 1.56 g/cm³
• LogP: -3.18050
• Storage Temp.: Sealed in dry,Room Temperature
• Water Solubility.: Soluble in water.

Purity/Quality:

10:1 Natural extract,95%, ^*data from raw suppliers

D-Pinitol ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C,F
• Hazard Codes: F,C
• Statements: 11-34
• Safety Statements: 22-24/25-45-36/37/39-26-16

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: suitable for coupling carboxyl- or aldehyde-containing ligands D-pinitol may be used as a starting material to prepare its azole nucleoside analogs. It may also be used in the preparation of 1D-1,5-dideoxy-1,5-difluoro-neo-inositol and 1D-1-deoxy-1-fluoro-myo-inositol.

Technology Process of D-Pinitol

There total 79 articles about D-Pinitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

3,5-di-O-benzyl-D-pinitol (1044736-09-5) → pinitol (10284-63-6)

Guidance literature:

With hydrogen; palladium on activated charcoal; In methanol;

DOI:10.1016/j.tetlet.2008.05.040

Reference yield: 100.0%

(1R,2R,3R,4S,5R,6S)-2,3,6-trihydroxy-4,5-di-O-isopropylidene-1-O-methylcyclohexane (130792-46-0) → pinitol (10284-63-6)

Guidance literature:

With hydrogenchloride; In water; acetone; for 0.5h; Ambient temperature;

Reference yield: 100.0%

(1L-1,2-di-O-benzoyl-4-O-methyl-chiro-inosityloxy)-(l)-menthoxyacetate (124647-09-2,124751-79-7) → pinitol (10284-63-6)

Guidance literature:

With water; triethylamine; In methanol; for 68h; Ambient temperature;

DOI:10.1016/S0040-4020(01)81025-5

upstream raw materials:

quebrachitol

methyl 2,3,4-tri-O-benzyl-D-glucopyranoside

(4S,5R,6S)-4,5,6-tris-benzyloxycyclohex-2-en-1-one

1-O-Allyl-2,3,4-tri-O-benzyl-D-chiro-inositol

Downstream raw materials:

1D-1,5-dideoxy-1,5-difluoro-4-O-methyl-neo-inositol

1,2:4,5-di-O-isopropylidene-3-O-methyl-D-chiro-inositol

3-O-methyl-1,2:5,6-bis-O-(1-methylethylidene)-D-chiro-inositol

4,5-O-(1',2'-dimethoxycyclohexane-1',2'-diyl)-3-O-methyl-D-chiro-inositol

Refernces

• 1、 Schweizer, Thomas F.,Horman, Ian. "PURIFICATION AND STRUCTURE DETERMINATION OF THREE α-D-GALACTOPYRANOSYLCYCLITOLS FROM SOYA BEAN". . p. 61 - 72. Retrieved 1981.
• 2、 Catelani, Giorgio,D'Andrea, Felicia,Griselli, Alessio,Guazzelli, Lorenzo,Legnani, Laura,Toma, Lucio. "A new stereoselective approach to a selectively protected derivative of d-pinitol and its evaluation as α-l-rhamnopyranose mimetic". . p. 4534 - 4536. Retrieved 2008/09/21.
• 3、 Jung, Pierre M. J.,Motherwell, William B.,Williams, Alvin S.. "Stereochemical observations on the bromate induced monobromopentahydroxylation of benzene by catalytic photoinduced charge transfer osmylation. A concise synthesis of (±)-pinitol". . p. 1283 - 1284. Retrieved 2007/10/03.