Technology Process of methyl(4-methyl-benzenethiolato){1,2-bis(diphenylphosphino)ethane}nickel
There total 1 articles about methyl(4-methyl-benzenethiolato){1,2-bis(diphenylphosphino)ethane}nickel which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
In
toluene;
byproducts: methane; Dropwise addn. of HSC6H4-p-CH3 to NiMe2(dpe) under protective gas (toluene, low temp.), evolution of CH4, stirring (room temp.),; filtn., washing (Et2O), drying (vacuo), elem. anal.;
- Guidance literature:
-
With
carbon monoxide;
In
dichloromethane;
Addn. of CO (ambient pressure) to metal complex (CH2Cl2, room temp.), stirring (4 h).; Trap-to-trap distn., GLC anal.;