Ni(CO)2{1,2-bis(diphenylphosphino)ethane}

Base Information

• Chemical Name: Ni(CO)2{1,2-bis(diphenylphosphino)ethane}
• CAS No.: 15793-01-8
• Molecular Formula: C₂₈H₂₄NiO₂P₂
• Molecular Weight: 513.135
• Mol file: 15793-01-8.mol

Synonyms:Ni(CO)2{1,2-bis(diphenylphosphino)ethane}

Chemical Property of Ni(CO)2{1,2-bis(diphenylphosphino)ethane}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ni(CO)2{1,2-bis(diphenylphosphino)ethane}

There total 28 articles about Ni(CO)2{1,2-bis(diphenylphosphino)ethane} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

(1,3-diphenylphosphinoethane)NiCH2CH(Me)CONH → 3-methylsuccinimide (5615-90-7,117307-07-0,128562-06-1,132295-22-8) + Ni(CO)2{1,2-bis(diphenylphosphino)ethane} (15793-01-8)

Guidance literature:

With carbon monoxide; In diethyl ether; N2 or Ar, the tube containing a soln. of Ni-compound was evacuated, CO introduced, stirred for 3 h; filtered; IR, NMR, GC;

DOI:10.1021/ja00545a009

Reference yield: 96.0%

((C6H5)2PCH2CH2P(C6H5)2)NiCH2CH(CH3)COO → Ni(CO)2{1,2-bis(diphenylphosphino)ethane} (15793-01-8) + 2-methylsuccinic anhydride (4100-80-5)

Guidance literature:

With carbon monoxide; In dichloromethane; Schlenk tube contg. CH2Cl2 soln. of nickel complex evacuated and 1 atm of CO introduced; analyzed by GLC, GC-mass, and IR;

DOI:10.1246/bcsj.57.2741

Reference yield: 94.0%

methyl(1,1,1,3,3,3-hexafluoro-2-propoxo){1,2-bis(diphenylphosphino)ethane}nickel (115981-40-3) → Ni(CO)2{1,2-bis(diphenylphosphino)ethane} (15793-01-8) + 1,1,1,3,3,3-hexafluoropropan-2-yl acetate (6919-79-5)

Guidance literature:

With carbon monoxide; In tetrahydrofuran; Addn. of CO (ambient pressure) to metal complex (THF, room temp.), stirring (2.5 h).; Trap-to-trap distn., GLC anal.;

upstream raw materials:

methyl(1,1,1,3,3,3-hexafluoro-2-propoxo){1,2-bis(diphenylphosphino)ethane}nickel

dibromo[1,2-bis(diphenylphosphino)ethane]nickel(II)

methyl(4-methyl-benzenethiolato){1,2-bis(diphenylphosphino)ethane}nickel

methyl(benzenethiolato){1,2-bis(diphenylphosphino)ethane}nickel

Downstream raw materials:

Ni⁽⁰⁾(1,2-bis(diphenylphosphino)ethane)2

{μ-(diphos)NiS2}Fe2(CO)6

Refernces

• 1、 Ariyananda, Piyal W. G.,Kieber-Emmons, Matthew T.,Yap, Glenn P. A.,Riordan, Charles G.. "Synthetic analogs for evaluating the influence of N-H...S hydrogen bonds on the formation of thioester in acetyl coenzyme a synthase". . p. 4359 - 4369. Retrieved 2009/10/16.
• 2、 Sacco, Adriano,Mastrorilli, Pietro. "Reactivity of Nickel(II) Diphosphine Complexes towards Alkoxides: a New Route to the Synthesis of Nickel(0) Compounds through Nickel(II) Alkoxides". . p. 2761 - 2764. Retrieved 2007/10/02.