metaphosphate

Base Information

• Chemical Name: metaphosphate
• CAS No.: 15389-19-2
• Molecular Formula: O₃P
• Molecular Weight: 78.972
• Mol file: 15389-19-2.mol

Synonyms:metaphosphate

Chemical Property of metaphosphate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of metaphosphate

There total 7 articles about metaphosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

PO2Cl(1-) + ozone (10028-15-6) → metaphosphate (15389-19-2) + PO4(1-) + chlorine dioxide (10049-04-4,25052-55-5) + chloride (16887-00-6) + chlorine monoxide (14989-30-1)

Guidance literature:

In neat (no solvent, gas phase); byproducts: Cl, PO3, O2; PO2Cl(1-) and O3 reacted in AFRL selected ion flow tube; rate constants and branching fractions measured at 163, 294, and 400 K at a He pressureof 0.4 Torr; Kinetics;

DOI:10.1021/jp047545q

Reference yield:

POCl(1-) + oxygen (80937-33-3) → metaphosphate (15389-19-2) + clorine (14700-96-0,14835-24-6,15723-23-6,16547-50-5,16885-04-4,16887-00-6,16904-11-3,16904-12-4,16999-02-3,20337-89-7,20499-73-4,22537-15-1,22537-27-5,22541-73-7,22541-74-8,24203-47-2,33944-49-9,34937-26-3,37352-90-2) + phosphite(1-) + chlorine monoxide (14989-30-1)

Guidance literature:

In neat (no solvent, gas phase); rate constants measured in a selected ion flow tube from 298 to 500 K; electron impact on POCl3 produced ions which mass selected by a quadrupole mass filter; POCl(1-) produced by reacting POCl2(1-) with H; O2 introduced at downstream inlet; Kinetics;

DOI:10.1021/jp045203e

Reference yield:

PO2Cl(1-) + oxygen (80937-33-3) → metaphosphate (15389-19-2) + PO4(1-) + clorine (14700-96-0,14835-24-6,15723-23-6,16547-50-5,16885-04-4,16887-00-6,16904-11-3,16904-12-4,16999-02-3,20337-89-7,20499-73-4,22537-15-1,22537-27-5,22541-73-7,22541-74-8,24203-47-2,33944-49-9,34937-26-3,37352-90-2) + chlorine monoxide (14989-30-1)

Guidance literature:

In neat (no solvent, gas phase); PO2Cl(1-) and O2 reacted in AFRL selected ion flow tube; rate constants and branching fractions measured at 163, 294, and 400 K at a He pressureof 0.4 Torr; Kinetics;

DOI:10.1021/jp047545q

upstream raw materials:

ammonium amidophosphate

oxygen

pyrophosphate tetraanion

ozone

Downstream raw materials:

meta-phosphoric acid

hydrogensulfate

Refernces

• 1、 Fernandez, Abel I.,Midey, Anthony J.,Miller, Thomas M.,Viggiano. "Reaction kinetics of PO2Cl-, PO2Cl 2-, POCl2- and POCl3 - with O2 and O3 from 163 to 400 K". . p. 9120 - 9125. Retrieved 2008/10/09.
• 2、 Shimasaki, Choichiro,Hara, Mitsunari. "Ueber die Reaktion von Harnstoff mit Ammoniumhydrogenamidophosphat unter dem Atmosphaerendruck". . p. 3613 - 3616. Retrieved 2007/10/02.