platinum propylenediamine dichloride

Base Information

• Chemical Name: platinum propylenediamine dichloride
• CAS No.: 33727-98-9
• Molecular Formula: C₃H₁₀Cl₂N₂Pt
• Molecular Weight: 340.112
• Mol file: 33727-98-9.mol

Synonyms:Platinum,dichloro(1,2-propanediamine)-, stereoisomer (6CI,8CI); Platinum,dichloro(1,2-propanediamine-N,N')-, (SP-4-3)-; 1,2-Propanediamine, platinumcomplex; NSC 157981

Chemical Property of platinum propylenediamine dichloride

Chemical Property:

• Vapor Pressure: 17.5mmHg at 25°C
• Boiling Point: 117.3°C at 760 mmHg
• Flash Point: 33.3°C
• PSA: 52.04000
• LogP: 1.82180

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of platinum propylenediamine dichloride

There total 7 articles about platinum propylenediamine dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

potassium tetrachloroplatinate(II) (10025-99-7) + 1,2-diaminopropan (78-90-0,10424-38-1) → [Pt((±)-1,2-propylenediamine)Cl2] (33727-98-9)

Guidance literature:

With HCl; In water; Pt-contg. compd. was dissolved in H2O and mixed with an equimolar amt. of the diamine ligand; pH was adjusted to ca. 3 (HCl); stirring at 80°C for 2 h; according to H. Hohmann, Inorg. Chim. Acta 174 (1990) 87; recrystn. from H2O; elem. anal.;

DOI:10.1016/j.poly.2010.12.039

Reference yield:

cis-(propane-1,2-diamine)diiodoplatinum(II) (171672-18-7) + potassium chloride → [Pt((±)-1,2-propylenediamine)Cl2] (33727-98-9)

Guidance literature:

cis-(propane-1,2-diamine)diiodoplatinum(II); With silver nitrate; In water; at 20 ℃; Darkness;

potassium chloride; In water;

DOI:10.1039/C8DT01946K

Reference yield:

cis-(propane-1,2-diamine)diiodoplatinum(II) (171672-18-7) + potassium chloride + water (7732-18-5) → [Pt((±)-1,2-propylenediamine)Cl2] (33727-98-9)

Guidance literature:

With silver sulfate; In water; byproducts: AgI; Ag:Pt=1.28:0.65 molar ratio, Pt compd. added to a soln. of Ag salt, stirred overnight at 40°C in the dark, filtered, KCl (excess) added, stored for 24 h; ppt. centrifuged, washed (cold water, ethanol, diethyl ether), dried (vac.);

DOI:10.1016/j.ica.2008.02.004

upstream raw materials:

potassium tetrachloroplatinate(II)

ferrocene

[Pt(propylenediamine)Cl₄]

cis-(propane-1,2-diamine)diiodoplatinum(II)

Refernces

• 1、 Sutton, Emily C.,Mcdevitt, Christine E.,Prochnau, Jack Y.,Yglesias, Matthew V.,Mroz, Austin M.,Yang, Min Chieh,Cunningham, Rachael M.,Hendon, Christopher H.,Derose, Victoria J.. "Nucleolar Stress Induction by Oxaliplatin and Derivatives". supporting information. p. 18411 - 18415. Retrieved 2019/11/19.
• 2、 Rajkovi?, Sne?ana,A?anin, Darko P.,?ivkovi?, Marija D.,Djuran, Milo? I.. "Synthesis of different pyrazine-bridged platinum(II) complexes and 1H NMR study of their catalytic abilities in the hydrolysis of the N-acetylated l-methionylglycine". . p. 42 - 47. Retrieved 2013/10/01.