acetonitril-O,O-sulfitomanganese(II) tricarbonyl

Base Information

• Chemical Name: acetonitril-O,O-sulfitomanganese(II) tricarbonyl
• CAS No.: 195135-41-2
• Molecular Formula: C₅H₃MnNO₆S
• Molecular Weight: 260.086
• Mol file: 195135-41-2.mol

Synonyms:acetonitril-O,O-sulfitomanganese(II) tricarbonyl

Chemical Property of acetonitril-O,O-sulfitomanganese(II) tricarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of acetonitril-O,O-sulfitomanganese(II) tricarbonyl

There total 3 articles about acetonitril-O,O-sulfitomanganese(II) tricarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 18.0%

fluorosulfonyl anhydride (13036-75-4) + sodium pentacarbonyl manganate (13859-41-1) → fluorosulfonyl fluoride (640723-20-2,2699-79-8,12769-73-2) + dimanganese decacarbonyl (10170-69-1) + acetonitril-O,O-sulfitomanganese(II) tricarbonyl (195135-41-2) + carbon monoxide (201230-82-2) + sulfur dioxide (7446-09-5,12143-17-8,89125-89-3)

Guidance literature:

In methyl cyclohexane; N2 atm.; cooling (1 h, -78°C), stirring (room temp., 72 h); evapn. (1E-4 torr), extraction (pentane, toluene (25°C, 20 torr)), acetonitrile (30°C, 50 torr)), concn., crystn. (-20°C);

Reference yield: 10.0%

fluorosulfonyl anhydride (13036-75-4) + sodium pentacarbonyl manganate (13859-41-1) → dimanganese decacarbonyl (10170-69-1) + acetonitril-O,O-sulfitomanganese(II) tricarbonyl (195135-41-2) + μ-disulfito-dimanganesedecacarbonyl

Guidance literature:

In acetonitrile; N2 atm.; cooling (-78°C), heating (30 min, -40°C), stirring (2 h); extraction (pentane, toluene), dissoln. (CH3CN), centrifugation, addn. of toluene; elem. anal.;

Reference yield: 10.0%

fluorosulfonyl anhydride (13036-75-4) + sodium pentacarbonyl manganate (13859-41-1) → fluorosulfonyl fluoride (640723-20-2,2699-79-8,12769-73-2) + sodium fluorosulfonate (14483-63-7) + acetonitril-O,O-sulfitomanganese(II) tricarbonyl (195135-41-2) + carbon monoxide (201230-82-2) + sulfur dioxide (7446-09-5,12143-17-8,89125-89-3)

Guidance literature:

In acetonitrile; N2 atm.; cooling (-78°C), heating (30 min, -40°C), stirring (2 h); extraction (pentane, toluene), dissoln. (CH3CN), centrifugation, addn. of toluene; elem. anal.;

upstream raw materials:

fluorosulfonyl anhydride

sodium pentacarbonyl manganate

Refernces