Acetoxy phenylmercury

Base Information

• Chemical Name: Acetoxy phenylmercury
• CAS No.: 62-38-4
• Molecular Formula: C8H8 Hg O2
• Molecular Weight: 336.74
• Hs Code.: 28521000
• UNII: OSX88361UX
• Mol file: 62-38-4.mol

Synonyms:Acetoxy phenylmercury;SCHEMBL49139;PHENYLMERCURIC ACETATE [II];PHENYLMERCURIC ACETATE [MI];PHENYLMERCURIC ACETATE [HSDB];PHENYLMERCURIC ACETATE [VANDF];PHENYL MERCURIC ACETATE [INCI];PHENYLMERCURIC ACETATE [MART.];PHENYLMERCURIC ACETATE [WHO-DD];PHENYLMERCURIC ACETATE [EP IMPURITY];P0192;PHENYLMERCURIC ACETATE [EP MONOGRAPH]

Chemical Property of Acetoxy phenylmercury

Chemical Property:

• Appearance/Colour: white crystalline powder
• Melting Point: 148-151 °C(lit.)
• PSA: 26.30000
• Density: 2,4 g/cm3
• LogP: 0.87250
• Storage Temp.: APPROX 4°C
• Solubility.: Slightly soluble in water, soluble in acetone and in alcohol.
• Water Solubility.: Soluble in alcohol, benzene and glacial acetic acid. Slightly soluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 338.023073
• Heavy Atom Count: 11
• Complexity: 71.7

Purity/Quality:

96% ^*data from raw suppliers

Phenylmercuric acetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Toxic by ingestion, inhalation, and skin absorption; strong irritant.
• Hazard Codes: T,N
• Statements: 25-34-48/24/25-50/53
• Safety Statements: 23-24/25-37-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=O)[O-].C1=CC=C(C=C1)[Hg+]
• Uses: antiulcer Herbicide; fungicide. Phenylmercuric acetate is used as catalyst; fungicide; herbicide; algicide; preservative in antibiotic eye drops, eye cosmetics, shampoos, etc.

Technology Process of Acetoxy phenylmercury

There total 16 articles about Acetoxy phenylmercury which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

phenyltrifluorosilane (368-47-8) → phenylmercuric acetate (62-38-4,8013-47-6)

Guidance literature:

With mercury(II) diacetate; In benzene; byproducts: CH3COOSiF3; addn. of trifluorophenylsilane to a suspn. of Hg(OCOCH3)2 in dry benzene, heating under reflux (80°C) for 10-15 min, on cooling pptn.;

DOI:10.1016/0022-328X(88)89077-6

Reference yield: 100.0%

phenyltrifluorosilane (368-47-8) + mercury(II) diacetate (1600-27-7) → phenylmercuric acetate (62-38-4,8013-47-6)

Guidance literature:

In benzene; byproducts: F3SiOCOCH3; addn. of PhSiF3 to suspn. of HgAc2, mixt. heated ( 10-15 min, 80°C); cooled, filtered;

Reference yield: 78.0%

C6H5Tl(OCOCH3)2 (20425-82-5) + mercury → phenylmercuric acetate (62-38-4,8013-47-6) + thallium(I) acetate (563-68-8)

Guidance literature:

In pyridine; mixed, stirred at 50°C for 6 h;

DOI:10.1007/BF00949503

upstream raw materials:

acetic acid

benzene

mercury(II) diacetate

sodium tetraphenyl borate

Downstream raw materials:

Cinnamyl acetate

(Z)-cinnamyl acetate

cinnamyl acetate

5-Phenyl-1-methyl-cyclopenten

Refernces

• 1、 -. "Process for producing pyromellitic acid". . . Retrieved 2008/06/13.
• 2、 -. "Preparation of N-substituted maleimides by use of tin catalysts". . . Retrieved 2008/06/13.