Thallium(I) acetate

Base Information

• Chemical Name: Thallium(I) acetate
• CAS No.: 563-68-8
• Molecular Formula: C2H3O2•Tl
• Molecular Weight: 263.428
• Hs Code.: 29152900
• Mol file: 563-68-8.mol

Synonyms:Acetic acid, thallium(1) salt;Acetic acid, thallium(1+) salt;Aceticacid,thallium(1+)salt;aceticacid,thallium(1++)salt;ethanoicacid,thalliumsalt;Rcra waste number U214;rcrawastenumberu214;Thallium acetate Tl(OAc)

Chemical Property of Thallium(I) acetate

Chemical Property:

• Appearance/Colour: White to off-white fine crystalline powder
• Vapor Pressure: 13.9mmHg at 25°C
• Melting Point: 124-128 °C
• Boiling Point: 117.1 °C at 760 mmHg
• Flash Point: 40 °C
• PSA: 26.30000
• Density: 3.68 g/cm³
• LogP: 0.01380
• Storage Temp.: Store at RT.
• Sensitive.: Hygroscopic
• Water Solubility.: Soluble in water, alcoholSoluble in cold water, ethanol, chloroform and ether. Sparingly soluble in hot water. Insoluble in acet
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 264.99556
• Heavy Atom Count: 5
• Complexity: 34.6

Purity/Quality:

99% ^*data from raw suppliers

AceticAcidThallium(1+)Salt ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T+,N
• Hazard Codes: T+,N
• Statements: 26/28-33-51/53
• Safety Statements: 13-28-45-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=O)O.[Tl]
• Uses: Acetic Acid Thallium(1+) Salt, is a Thalum salt, considere to be a hazardous material.It can be used as in Chemical Synthesis, Micro/NanoElectronics, and Materials Science. Rodenticide, insecticide; fireworks dye; in optical glass; depilatory. Thallium acetate is used in high specific gravity solutions to separate ore constituents by flotation. It was formerly used as a depilating agent by dermatologists via oral administration in cases of ringwormof the scalp, causinga number ofdeathsand poisonings.Thallium(I) acetate (0.1M) is used to enhance phosphorescence emission on laserinduced room-temperature phosphorimetry.

Technology Process of Thallium(I) acetate

There total 22 articles about Thallium(I) acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

C6H5Tl(OCOCH3)2 (20425-82-5) + mercury → phenylmercuric acetate (62-38-4,8013-47-6) + thallium(I) acetate (563-68-8)

Guidance literature:

In pyridine; mixed, stirred at 50°C for 6 h;

DOI:10.1007/BF00949503

Reference yield: 65.0%

ethyl 4--3,5-dimethylpyrrole-2-carboxylate (131992-04-6) + copper(ll) bromide (7789-45-9) → ethyl 4-bromo-3,5-dimethylpyrrole-2-carboxylate (5408-07-1) + thallium(I) acetate (563-68-8)

Guidance literature:

In 1,4-dioxane; byproducts: ethyl 3,5-dimethylpyrrole-2-carboxylate; addn. soln. of Tl compound to soln. of Cu(II) compound, stirring (3 h, 80°C); cooling, filtration off inorganic salts, filtrate washing (dioxane), extn. (Et2O), drying (Na2SO4); m. p.;

Reference yield: 42.0%

ethyl 4--3-ethyl-5-methylpyrrole-2-carboxylate (131992-05-7) + copper(ll) bromide (7789-45-9) → ethyl 4-bromo-3-ethyl-5-methylpyrrole-2-carboxylate (133509-03-2) + thallium(I) acetate (563-68-8)

Guidance literature:

In 1,4-dioxane; byproducts: ethyl 3,5-dimethylpyrrole-2-carboxylate; addn. soln. of Tl compound to soln. of Cu(II) compound, stirring (2 h, 80°C); cooling, filtration off inorganic salts, filtrate washing (dioxane), extn. (Et2O), drying (Na2SO4); m. p.;

upstream raw materials:

thallium(III) triacetate

acetone

acetic acid

thallium (I) ethoxide

Downstream raw materials:

t-2-iodo-1-methylcyclohexan-r-1-yl acetate

trans-2-iodomethylcyclohexyl acetate

trimethylsilyl acetate

3-phenylpropanoic acid methyl ester

Refernces

• 1、 Gun'kin. "Organothallium compounds. Reaction of phenylhydrazine with thallium(III) oxide". . p. 824 - 825. Retrieved 2007/10/03.
• 2、 Kraus, H.-J.,Werner, H.,Krueger, C.. "Synthesis and Structure of C5Me5Pd(PR3)X: Palladium Complexes with an Unsymmetrically Bonded Pentamethylcyclopentadienyl Ring". . p. 733 - 737. Retrieved 2007/10/02.