2-Bromoallylamine

Base Information

• Chemical Name: 2-Bromoallylamine
• CAS No.: 6943-51-7
• Molecular Formula: C3H6 Br N
• Molecular Weight: 135.991
• European Community (EC) Number: 834-859-5
• NSC Number: 53432
• UNII: PV82C960TE
• DSSTox Substance ID: DTXSID90219588
• Nikkaji Number: J75.002F
• Wikidata: Q83096541
• Mol file: 6943-51-7.mol

Synonyms:2-bromoprop-2-en-1-amine;2-Bromoallylamine;6943-51-7;2-Bromo-2-propen-1-amine;ALLYLAMINE, 2-BROMO-;2-Propen-1-amine, 2-bromo-;C3H6BrN;NSC 53432;BRN 1736932;PV82C960TE;MFCD00015930;NSC-53432;NSC53432;UNII-PV82C960TE;C3-H6-Br-N;SCHEMBL321183;DTXSID90219588;BCP31260;3-AMINO-2-BROMO-1-PROPENE;AKOS010093632;AS-43779;LS-16386;SY122662;CS-0251869;EN300-56453;Z600439032;2-Propen-1-amine,2-bromo- pound>>2-Bromo-2-propen-1-amine

Chemical Property of 2-Bromoallylamine

Chemical Property:

• Vapor Pressure: 3.04mmHg at 25°C
• Boiling Point: 155.4°C at 760 mmHg
• Flash Point: 47.8°C
• Density: 1.514g/cm³
• XLogP3: 0.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 134.96836
• Heavy Atom Count: 5
• Complexity: 42.2

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=C(CN)Br

Technology Process of 2-Bromoallylamine

There total 6 articles about 2-Bromoallylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

2-(2-bromooallyl)isoindoline-1,3-dione → 2-bromoallylamine (6943-51-7)

Guidance literature:

2-(2-bromooallyl)isoindoline-1,3-dione; With hydrazine hydrate; In ethanol; for 1h; Reflux;

With hydrogenchloride; In water; for 1h;

DOI:10.1039/c3cc40757h

Reference yield:

1,2,3-tribromopropane (96-11-7) → 2-bromoallylamine (6943-51-7)

Guidance literature:

With ethanol; ammonia; at 100 ℃;

Reference yield:

→ 2-bromoallylamine (6943-51-7)

Guidance literature:

With potassium hydroxide;

upstream raw materials:

1,2,3-tribromopropane

2-bromoallyl bromide

2,3-dibromopropan-1-amine

Downstream raw materials:

N-<2-Brom-allyl>-2-hydroxy-3-butenylamin

N-(2-bromoallyl)-4-methylbenzenesulfonamide

N-(2-bromoallyl)benzamide

N-(benzylidene)-2-bromo-2-propenylamine

Refernces

• 1、 Fort, Diego A.,Woltering, Thomas J.,Nettekoven, Matthias,Knust, Henner,Bach, Thorsten. "Conformationally restricted pyrrolidines by intramolecular [2+2] photocycloaddition reactions". supporting information. p. 2989 - 2991. Retrieved 2013/05/09.