Technology Process of trans-9-Methyl-7-decenoic acid
There total 2 articles about trans-9-Methyl-7-decenoic acid which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 3 steps
1: DIBAL / toluene / 1 h / -78 °C
2: KOtBu / dimethylformamide / Ambient temperature
3: 79 percent / CrO3 / acetone / 1) 0 deg C, 30 min, 2)r.t., 1.5 h
With
chromium(VI) oxide; potassium tert-butylate; diisobutylaluminium hydride;
In
N,N-dimethyl-formamide; acetone; toluene;
- Guidance literature:
-
Multi-step reaction with 4 steps
1: conc. H2SO4 / Heating
2: pyridinium chlorochromate (PCC), sodium acetate / CH2Cl2 / 1.5 h / Ambient temperature
3: 1.) t-BuOK / 1.) DMF, RT, 5 min, 2.) a) RT, 20 h, b) 90 deg C, 1 h
4: aq. KOH / ethanol / 1 h / Heating
With
potassium hydroxide; sulfuric acid; potassium tert-butylate; sodium acetate; pyridinium chlorochromate;
In
ethanol; dichloromethane;
DOI:10.1021/jo00240a024
- Guidance literature:
-
Multi-step reaction with 3 steps
1: thionyl chloride / 1.) RT, 18 h, 2.) 100 deg C, 30 min
2: diethyl ether / 72 h / Ambient temperature
3: H2 / 10percent Pd/C / ethanol / 4 h / 760 Torr
With
thionyl chloride; hydrogen;
palladium on activated charcoal;
In
diethyl ether; ethanol;
DOI:10.1021/jo00240a024
