MCPA-sodium

Base Information

• Chemical Name: MCPA-sodium
• CAS No.: 3653-48-3
• Deprecated CAS: 11100-01-9,11114-06-0,11114-06-0
• Molecular Formula: C9H9 Cl O3 . Na
• Molecular Weight: 222.603
• Hs Code.: 2918990090
• European Community (EC) Number: 222-895-9
• UN Number: 2588
• UNII: 4E2KB6UGRM
• DSSTox Substance ID: DTXSID2034700
• Nikkaji Number: J3.055D
• Wikidata: Q27259471
• ChEMBL ID: CHEMBL2135017
• Mol file: 3653-48-3.mol

Synonyms:MCPA-sodium;MCPA sodium salt;3653-48-3;MCPA sodium;Methoxone sodium salt;Sodium MCPA;Phenoxylene;Chwastoks;Chwastox;Dicotex;Dikoteks;Dikotex;Estermine;Metaxone;Methoxon;2M-4KH sodium salt;MCP sodium salt;Agroxone 3;Methoxone 30;Chwastox 80;Dicotex 80;Dikotex 30;Hedonal M80;Chwastox plynny 30;Hedonal M 80;DIKOTEX P;MCPA-sodium [ISO];Caswell No. 557K;Sodium (4-chloro-2-methylphenoxy)acetate;SYS 67ME;4-Chloro-2-methylphenoxyacetic acid sodium salt;Sodium 2-methyl-4-chlorophenoxyacetate;Sodium (2-methyl-4-chlorophenoxy)acetate;sodium;2-(4-chloro-2-methylphenoxy)acetate;U 46M;(p-Chloro-o-tolyloxy)acetic acid sodium salt;EINECS 222-895-9;UNII-4E2KB6UGRM;4E2KB6UGRM;EPA Pesticide Chemical Code 030502;Acetic acid, (4-chloro-2-methylphenoxy)-, sodium salt;4-Chloro-o-tolyloxyacetic acid, sodium salt;DTXSID2034700;(4-Chloro-2-methylphenoxy) acetate sodium salt;(2-Methyl-4-chlorophenoxy)acetic acid, sodium salt;Acetic acid, ((4-chloro-o-tolyl)oxy)-, sodium salt;4-Chloro-2-methylphenoxyacetate sodium salt;MCPA sodium 100 microg/mL in Acetonitrile:Methanol;Acetic acid, 2-(4-chloro-2-methylphenoxy)-, sodium salt (1:1);MCPASODIUM;Acetic acid, [(4-chloro-o-tolyl)oxy]-, sodium salt;NA MCPA;AGROXONE-3;C9H8ClO3.Na;sodium 2-(4-chloro-2-methylphenoxy)acetate;DIKOTEX-30;MCPA SODIUM SALT [MI];SCHEMBL5475058;CHEMBL2135017;DTXCID0014700;STAPBGVGYWCRTF-UHFFFAOYSA-M;2M-4X;Tox21_302386;AKOS003052577;AKOS022190758;NCGC00164000-01;NCGC00255502-01;CAS-3653-48-3;(4-chloro-2-methylphenoxy)acetate sodium salt;(4-CHLORO-2-METHYLPHENOXY)ACETATE SODIUM;W-109924;Q27259471;2-METHYL-4-CHLOROPHENOXYACETIC ACID SODIUM SALT

Chemical Property of MCPA-sodium

Chemical Property:

• Vapor Pressure: 8.42E-05mmHg at 25°C
• Melting Point: 118-119oC
• Boiling Point: 327°Cat760mmHg
• Flash Point: 151.6°C
• PSA: 49.36000
• Density: g/cm³
• LogP: 0.77710
• Storage Temp.: 0-6°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 222.0059661
• Heavy Atom Count: 14
• Complexity: 189

Purity/Quality:

99.9% ^*data from raw suppliers

MCPA sodium salt monohydrate PESTANAL ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=C(C=CC(=C1)Cl)OCC(=O)[O-].[Na+]
• Uses: Herbicide.

Technology Process of MCPA-sodium

There total 6 articles about MCPA-sodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

→ sodium 2-methyl-4-chlorophenoxyacetate (3653-48-3)

Guidance literature:

Reference yield: 98.0%

2-(4-chloro-2-methylphenoxy)ethanol (36220-29-8) → sodium 2-methyl-4-chlorophenoxyacetate (3653-48-3)

Guidance literature:

With sodium hydroxide; oxygen; bismuth(III) nitrate; palladium on activated charcoal; at 90 ℃; for 2h;

Reference yield:

n-butyl 4-chloro-2-methylphenoxyacetate (1713-12-8) → sodium 2-methyl-4-chlorophenoxyacetate (3653-48-3)

Guidance literature:

With sodium hydroxide; at 70 ℃; for 4h;

upstream raw materials:

2-(4-chloro-2-methylphenoxy)ethanol

2-methyl-4-chlorophenol

sodium monochloroacetic acid

ortho-cresol

Downstream raw materials:

4-dodecyl-4-methyl-morpholine (4-chloro-2-methylphenoxy)acetate

8-hydroxy-1-octyl-quinolinium (4-chloro-2-methylphenoxy)acetate

MCPA

cyclohexyldimethyltetradecyloxymethylammonium 4-chloro-2-methylphenoxyacetate

Refernces

• 1、 He, Xingrui,Yu, Zhaonan,Jiang, Shaojie,Zhang, Peizhi,Shang, Zhicai,Lou, Yonggen,Wu, Jun. "Finding new elicitors that induce resistance in rice to the white-backed planthopper Sogatella furcifera". supporting information. p. 5601 - 5603. Retrieved 2015/11/17.
• 2、 Fiege, Helmut,Wedemeyer, Karlfried. "Aktivierung von Oxidationen mit Sauerstoff an Platinmetallen am Beispiel der Umwandlung von 2-Phenoxyethanolen zu Phenoxyessigsaeuren". . p. 812 - 813. Retrieved 2007/10/02.