C₁₉H₂₅NOS

Base Information

• Chemical Name: C₁₉H₂₅NOS
• CAS No.: 1023378-05-3
• Molecular Formula: C₁₉H₂₅NOS
• Molecular Weight: 315.48
• Mol file: 1023378-05-3.mol

Synonyms:C₁₉H₂₅NOS

Chemical Property of C₁₉H₂₅NOS

Chemical Property:

Purity/Quality:

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Technology Process of C₁₉H₂₅NOS

There total 1 articles about C₁₉H₂₅NOS which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

cyclohexa-1,4-diene (1165952-92-0) + (E)-(S)-2-methyl-propane-2-sulfinic acid [(E)-3-phenyl-prop-2-enylidene]-amide (186249-75-2) → C19H25NOS (1023378-05-3) + (S)-2-methyl-propane-2-sulfinic acid ((E)-(R)-1-(R)-cyclohexa-2,4-dienyl-3-phenylallyl)-amide (1023377-86-7)

Guidance literature:

cyclohexa-1,4-diene; With N,N,N,N,-tetramethylethylenediamine; (2-methylpropyl)lithium; In tetrahydrofuran; hexane; at -78 ℃; for 1.5h; Inert atmosphere;

With magnesium chloride; In tetrahydrofuran; for 3h; Inert atmosphere;

(E)-(S)-2-methyl-propane-2-sulfinic acid [(E)-3-phenyl-prop-2-enylidene]-amide; In tetrahydrofuran; at -78 ℃; for 0.5h; diastereoselective reaction; Inert atmosphere;

DOI:10.1021/ol800478q

upstream raw materials:

cyclohexa-1,4-diene

(E)-(S)-2-methyl-propane-2-sulfinic acid [(E)-3-phenyl-prop-2-enylidene]-amide

Refernces