Technology Process of N-allyl-3-butenamide
There total 1 articles about N-allyl-3-butenamide which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
dicobalt octacarbonyl;
In
methanol;
at 25 ℃;
for 18h;
Product distribution;
Irradiation;
other catalyst, other solvents, other gas, other substrates;
DOI:10.1246/cl.1991.1397
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: 80 percent / RuCl2(PCy3)2CHPh / CH2Cl2 / 12 h / Heating
2.1: n-BuLi / tetrahydrofuran; hexane / 0.25 h / -78 °C
2.2: 94 percent / tetrahydrofuran; hexane / 0.17 h / -78 °C
3.1: 91 percent / MCPBA / CH2Cl2 / 15 h / 20 °C
4.1: 99 percent / t-BuOK / 2-methyl-propan-2-ol / 20 °C
5.1: 98 percent / TMSOTf / CH2Cl2 / 0.08 h / 0 °C
With
Grubbs catalyst first generation; n-butyllithium; trimethylsilyl trifluoromethanesulfonate; potassium tert-butylate; 3-chloro-benzenecarboperoxoic acid;
In
tetrahydrofuran; hexane; dichloromethane; tert-butyl alcohol;
DOI:10.1021/ol010183+
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: 80 percent / RuCl2(PCy3)2CHPh / CH2Cl2 / 12 h / Heating
2.1: n-BuLi / tetrahydrofuran; hexane / 0.25 h / -78 °C
2.2: 94 percent / tetrahydrofuran; hexane / 0.17 h / -78 °C
3.1: 91 percent / MCPBA / CH2Cl2 / 15 h / 20 °C
4.1: 99 percent / t-BuOK / 2-methyl-propan-2-ol / 20 °C
5.1: 47 percent / lipase PPL; molecular sieves 4 Angstroem / toluene / 96 h / 20 °C
6.1: H2 / Pd/C / ethyl acetate / 10 h / 20 °C
With
Grubbs catalyst first generation; n-butyllithium; lipase PPL; 4 A molecular sieve; potassium tert-butylate; hydrogen; 3-chloro-benzenecarboperoxoic acid;
palladium on activated charcoal;
In
tetrahydrofuran; hexane; dichloromethane; ethyl acetate; toluene; tert-butyl alcohol;
DOI:10.1021/ol010183+
