POLY(VINYL FLUORIDE)

Base Information

• Chemical Name: POLY(VINYL FLUORIDE)
• CAS No.: 24981-14-4
• Molecular Formula: C₂H₃F
• Molecular Weight: 46.0442
• Mol file: 24981-14-4.mol

Synonyms:Ethylene,fluoro-, homopolymer (6CI); Ethylene, fluoro-, polymers (8CI); Dalvor 720;Dyflor L 90; EP-L 90; Excelar 2000; Fluoroethylene polymer; J 328; Lumiflon F301; Monofluoroethylene polymer; PV 116; PVF; Poly(fluoroethylene); Poly(vinylfluoride); TTR 10BG3; TWH 20BE3; Tedlar; Tedlar 100BG15UT; Tedlar 100BG300T;Tedlar 100BG30TR; Tedlar 100BG30UT; Tedlar 100BG30WH; Tedlar 100SM30MR; Tedlar100SM30PC; Tedlar 150BL30HB; Tedlar 150BL30WH; Tedlar 20; Tedlar 200BG15UT;Tedlar 200BL30CW; Tedlar 200SG40TR; Tedlar 400BS30WH; Tedlar 50; Tedlar50AM20LH; Tedlar 88N809; Tedlar FM; Tedlar PVF; Tedlar SG 40TR; Tedlar SP;Tedlar T-TR 20SG; Tedlar TAW 15AH8; Tedlar TBK 15B9; Tedlar TCC 15SL3; TedlarTCM 15SL3; Tedlar TDS 15BL3; Tedlar TES 20BE5; Tedlar TFM 05AL2; Tedlar TGH15BL3; Tedlar TGY 15SL3; Tedlar TGY 20BE3; Tedlar THB 15BL3; Tedlar TJW 30AM9;Tedlar TMB 20BE3; Tedlar TPD 20BE5; Tedlar TR 10AH8; Tedlar TR 10AM8; Tedlar TR10BG3; Tedlar TR 10SG3; Tedlar TR 15BG5; Tedlar TST 20SG4; Tedlar TTR 10SG3;Tedlar TUT 10AG3; Tedlar TUT 10BG3; Tedlar TVW 10AH8; Tedlar TW 10B53; TedlarTWH 15BL3; Tedlar TWH 15SL3; Tedlar UT; Tetra-film; Vinyl fluoride homopolymer;Vinyl fluoride polymer

Chemical Property of POLY(VINYL FLUORIDE)

Chemical Property:

• Melting Point: 200 °C (approx)
• PSA: 0.00000
• LogP: 1.09940

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of POLY(VINYL FLUORIDE)

There total 82 articles about POLY(VINYL FLUORIDE) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 19.9%

1,1-difluoroethane (75-37-6) → ethene (74-85-1) + 1-fluoroethylene (75-02-5,24981-14-4) + acetylene (74-86-2,25067-58-7)

Guidance literature:

With hydrogen fluoride; Guingnet's green; at 250 - 400 ℃; for 10 - 129h;

Reference yield:

1-chloro-1-fluoroethane (2317-91-1) → 1-fluoroethylene (75-02-5,24981-14-4) + fluoroethyne (2713-09-9) + chloroacetylene (593-63-5) + Vinylidene fluoride (75-38-7) + acetylene (74-86-2,25067-58-7)

Guidance literature:

at 1143.9 ℃; under 703 Torr; Product distribution; infrared multiphoton decomposition, effect of reaction pressure, pulse energy, additives, N₂ and H₂ pressure;

DOI:10.1246/bcsj.58.1358

Reference yield:

ethene (74-85-1) + monofluorocarbene (13453-52-6) → methylene (2465-56-7) + Methyl fluoride (593-53-3) + 1-fluoroethylene (75-02-5,24981-14-4) + 1-fluoropropene (406-33-7) + acetylene (74-86-2,25067-58-7)

Guidance literature:

In gas; Rate constant; Thermodynamic data; Ambient temperature; Irradiation; ΔH;

upstream raw materials:

diethyl ether

1,1-difluoro-2-iodoethane

1,2-bromofluoroethane

1,1-difluoroethane

Downstream raw materials:

1,3-dibromo-1,1,3-trifluoro-propane

thioacetic acid-2-fluoroethyl ester

1,6-dibromo-2-chloro-1,1,2,4,6-pentafluoro-hexane

1,1,2,4-tetrafluoro-4-iodo-but-1-ene

Refernces

• 1、 Robinson, Gary N.,Continetti, Robert E.,Lee, Yuan T.. "The translational energy dependence of the F + C2H4 -> H + C2H3F reaction cross section near threshold". . p. 275 - 284. Retrieved 1990.
• 2、 Diaz, L.,Santos, M.,Sigueenza, C. L.,Simeonov, S. A.,Gonzalez-Diaz, P. F.,et al.. "Infrared Laser-induced Chemistry of Chlorodifluoromethane-Silane Mixtures at Two Irradiating Wavelengths". . p. 3907 - 3912. Retrieved 1993.
• 3、 Mcrae,Ivanco,Goodale. "Two-color multiphoton decomposition of 1-bromo 2-fluoroethane". . p. 147 - 158. Retrieved 1994.
• 4、 Slagle, Irene R.,Gutman, David. "Extent of the Displacement Route in the Reactions of Fluorine Atoms with Ethylene. Vinyl Chloride, and Vinyl Bromide". . p. 1818 - 1821. Retrieved 1983.
• 5、 Cadman, Philip,Owen, Howell L.. "Reactions of Fluoromethyl Radicals". . p. 3087 - 3106. Retrieved 1981.
• 6、 Raff, Lionel M.. "Computational Studies of the Bimolecular Reaction Dynamics of the C2H4 + F2 System". . p. 141 - 147. Retrieved 1988.
• 7、 Xu, Hui,Kiefer, John H.,Sivaramakrishnan, Raghu,Giri, Binod R.,Tranter, Robert S.. "Shock tube study of dissociation and relaxation in 1,1-difluoroethane and vinyl fluoride". . p. 4164 - 4176. Retrieved 2007.
• 8、 Tang, Haodong,Dang, Mingming,Li, Yuzhen,Li, Lichun,Han, Wenfeng,Liu, Zongjian,Li, Ying,Li, Xiaonian. "Rational design of MgF2 catalysts with long-term stability for the dehydrofluorination of 1,1-difluoroethane (HFC-152a)". . p. 23744 - 23751. Retrieved 2019.
• 9、 -. "PRODUCTION METHOD FOR FLUORO-ETHANE AND PRODUCTION METHOD FOR FLUORO-OLEFIN". Paragraph 0087. . Retrieved 2021/10/15.