2-Propenoic acid, 4-(oxiranylmethoxy)butyl ester

Base Information

• Chemical Name: 2-Propenoic acid, 4-(oxiranylmethoxy)butyl ester
• CAS No.: 119692-59-0
• Deprecated CAS: 1646876-06-3,2137054-05-6
• Molecular Formula: C10H16 O4
• Molecular Weight: 200.235
• European Community (EC) Number: 437-510-1
• DSSTox Substance ID: DTXSID50888895
• Nikkaji Number: J1.110.278F
• Mol file: 119692-59-0.mol

Synonyms:119692-59-0;4-(Oxiran-2-ylmethoxy)butyl acrylate;2-Propenoic acid, 4-(oxiranylmethoxy)butyl ester;2-Propenoic acid, 4-(2-oxiranylmethoxy)butyl ester;4-(oxiran-2-ylmethoxy)butyl Prop-2-enoate;4-hydroxybutyl acrylate glycidyl ether;4HBAGE;SCHEMBL268151;DTXSID50888895;USWANRSZMQLWTG-UHFFFAOYSA-N;4-hydroxybutyl acrylate glycidylether;MFCD30474906;SY271730;WS-00791;CS-0069855;4-[(oxiran-2-yl)methoxy]butyl prop-2-enoate;D85270

Chemical Property of 2-Propenoic acid, 4-(oxiranylmethoxy)butyl ester

Chemical Property:

• Vapor Pressure: 0.002mmHg at 25°C
• Boiling Point: 287.531°C at 760 mmHg
• Flash Point: 123.267°C
• PSA: 48.06000
• Density: 1.077g/cm³
• LogP: 0.91120
• XLogP3: 1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 9
• Exact Mass: 200.10485899
• Heavy Atom Count: 14
• Complexity: 191

Purity/Quality:

99.9% ^*data from raw suppliers

2-Propenoicacid,4-(oxiranylmethoxy)butylester ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC(=O)OCCCCOCC1CO1
• Description: 4-Hydroxybutyl Acryrate Glycidyl Ether with a glycidylether group at the end of a longer alkyl chain, gives excellent scratch resistance due to its high crosslinking ratio and unique flexibility.This copolymer has good acid rain resistance.It is used in Paint and coating materials,UV/EB curable composition.

Technology Process of 2-Propenoic acid, 4-(oxiranylmethoxy)butyl ester

There total 4 articles about 2-Propenoic acid, 4-(oxiranylmethoxy)butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1,4-butanediol monoglycidyl ether (4711-95-9) + ethyl acrylate (140-88-5,9003-32-1) → butanediol monoglycidyl ether acrylate (119692-59-0)

Guidance literature:

1,4-butanediol monoglycidyl ether; ethyl acrylate; With titanium(IV) isopropylate; at 95 ℃; for 4h; under 300.03 Torr; Reflux;

With 4-methoxy-phenol; under 300.03 Torr;

Reference yield: 83.7%

2-methoxyethyl acrylate (3121-61-7,28628-64-0) + 1,4-butanediol monoglycidyl ether (4711-95-9) → butanediol monoglycidyl ether acrylate (119692-59-0)

Guidance literature:

With tetrabutoxytitanium; 4-methoxy-phenol; In o-xylene; at 80 - 90 ℃; under 75.0075 Torr;

Reference yield: 70.4%

tetrahydrofurfuryl acrylate (2399-48-6,29324-52-5) + 1,4-butanediol monoglycidyl ether (4711-95-9) → butanediol monoglycidyl ether acrylate (119692-59-0)

Guidance literature:

With tetrabutoxytitanium; 4-methylisopropylbenzene; 4-methoxy-phenol; at 89 - 102 ℃; under 30.003 Torr;

upstream raw materials:

1,4-butanediol monoglycidyl ether

ethyl acrylate

acrylic acid methyl ester

2-methoxyethyl acrylate

Downstream raw materials:

2-benzoyl-benzoic acid 3-(4-acryloyloxy-butoxy)-2-hydroxy-propyl ester

C₃₉H₄₅NO₈

acrylic acid 4-[3-(4-benzoyl-phenoxy)-2-hydroxy-propoxy]butyl ester

Refernces

• 1、 -. "(Meth) acrylate, an epoxy group end manufacturing method". Paragraph 0044-0046. . Retrieved 2017/01/02.