Ytterbium bromide (YbBr3)

Base Information

• Chemical Name: Ytterbium bromide (YbBr3)
• CAS No.: 13759-89-2
• Deprecated CAS: 2755079-16-2
• Molecular Formula: Br3Yb
• Molecular Weight: 412.752
• European Community (EC) Number: 237-350-0
• DSSTox Substance ID: DTXSID8065610
• Wikipedia: Ytterbium(III) bromide
• Wikidata: Q424877
• Mol file: 13759-89-2.mol

Synonyms:13759-89-2;Ytterbium bromide;tribromoytterbium;Ytterbium bromide (YbBr3);Ytterbium tribromide;YbBr3;YTTRIUM(III) BROMIDE HYDRATE;Yttrium(iii)bromide hydrate;DTXSID8065610;Ytterbium(III) bromide, anhydrous;Ytterbium(III) bromide, ultra dry;EINECS 237-350-0;MFCD00049613;Q424877;Ytterbium(III) bromide, anhydrous, powder, 99.99% trace metals basis

Chemical Property of Ytterbium bromide (YbBr3)

Chemical Property:

• Melting Point: >300 °C(lit.)
• Sensitive.: Hygroscopic
• Water Solubility.: Soluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 412.69183
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Yttrium(III) bromide hydrate 99.9% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: Br[Yb](Br)Br

Technology Process of Ytterbium bromide (YbBr3)

There total 14 articles about Ytterbium bromide (YbBr3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(C6H5)2(C4H8O)Yb(C6H5)3Yb(C4H8O)3 → ytterbium bromide (13759-89-2)

Guidance literature:

With Br₂; In tetrahydrofuran; byproducts: C6H5Br; addn. of Br2 in THF to a soln. of the starting complex in THF under vac.; centrifuging, decanting from the ppt. of YBr3;

DOI:10.1016/0022-328X(92)83316-A

Reference yield: 99.0%

[Yb(water)8](Br)3 → ytterbium bromide (13759-89-2)

Guidance literature:

In neat (no solvent, solid phase); byproducts: H2O; Schlenk techniques; heating Yb compd. under vacuum (1E-3 Torr);

DOI:10.1016/j.poly.2010.02.027

Reference yield: 98.0%

Ph3SnYb(THF)2(μ-Ph)3Yb(THF)3 → triphenyltin bromide (962-89-0) + diphenyltin(IV) dibromide (4713-59-1) + phenyltin(IV) tribromide (7727-17-5) + ytterbium bromide (13759-89-2)

Guidance literature:

With bromine; In 1,2-dimethoxyethane; byproducts: bromobenzene; bromobenzene detected by GLC;

DOI:10.1016/0022-328X(91)86429-T

upstream raw materials:

hydrogen bromide

bromine

ytterbium(III) tribromide (hydrated)

disulfur dichloride

Downstream raw materials:

BrYbC₆H₄YbBr

Yb(III)(dibenzylsulphoxide)5(bromide)3

ClYbC₆H₄YbCl

BrYbC₆H₄YbCl

Refernces

• 1、 Hehlen, Markus P.,Kuditcher, Amos,Rand, Stephen C.,Tischler, Michael A.. "Electron-phonon interactions in CsCdBr3=Yb3+". . p. 4886 - 4892. Retrieved 1997.
• 2、 Wang, Zhi-Chang,Yu, Jin. "Systematics and anomalies in rare earth/aluminum bromide vapor complexes: Thermodynamic properties of the vapor complexes LnAl3Br12 from Ln = Sc to Ln = Lu". . p. 4248 - 4255. Retrieved 2008/10/09.