cobalt acetate

Base Information

• Chemical Name: cobalt acetate
• CAS No.: 55881-15-7
• Molecular Formula: C₂H₃O₂*Co
• Molecular Weight: 118.038
• Mol file: 55881-15-7.mol

Synonyms:cobalt acetate

Chemical Property of cobalt acetate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of cobalt acetate

There total 48 articles about cobalt acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

cobalt(III) acetate + cyclohexene (110-83-8) → rac-3-acetoxycyclohexene (76644-52-5,76704-31-9,14447-34-8,62247-41-0) + cobalt(II) acetate (71-48-7,917-69-1,5931-89-5,55881-15-7,68931-68-0,68931-69-1,93029-27-7)

Guidance literature:

With potassium bromide; In acetic acid; at 80 ℃; for 1h;

Reference yield: 39.0%

(PPh3)3CoH(N2) (21373-88-6,16920-54-0) → methane (34557-54-5,27936-85-2) + cobalt acetate (55881-15-7) + nitrogen (7727-37-9) + hydrogen (1333-74-0) + ethyl acetate (141-78-6)

Guidance literature:

With acetic acid anhydride; In toluene; Ac2O added to toluene soln. of CoH(N2)(PPh3)3, evacuated, stirred at room temp. for 1 day; hexane added, recrystd. from pyridine;

DOI:10.1021/ja00263a007

Reference yield:

cobalt(II) diacetate tetrahydrate (6147-53-1) → cobalt(II) acetate (71-48-7,917-69-1,5931-89-5,55881-15-7,68931-68-0,68931-69-1,93029-27-7)

Guidance literature:

In neat (no solvent); byproducts: H2O; heated at different heating rates (0.5, 1, 2, 5, 10 K/ min) to 325-421 K; Kinetics;

DOI:10.1016/0040-6031(89)85463-2

upstream raw materials:

acetic anhydride

acetic acid

cyclohexene

cobalt(II) carbonate

Downstream raw materials:

cobalt(II)(bis(salicylidene)ethylenediamine)

acetic anhydride

cobalt(III) acetate

benzaldehyde

Refernces

• 1、 Sumner Jr., Charles E.,Morrill, Kent A.,Howell, Jeff S.,Little, James. "Factors affecting the selectivity of the oxidation of methyl p-toluate by cobalt(III)". . p. 2190 - 2195. Retrieved 2008.
• 2、 Tai, Serene,Maskrey, Taber S.,Nyalapatla, Prasanth R.,Wipf, Peter. "Co(II)-salen catalyzed stereoselective cyclopropanation of fluorinated styrenes". . p. 1014 - 1027. Retrieved 2019/11/14.
• 3、 Munzert, Stefanie Martina,Stier, Simon P.,Schwarz, Guntram,Weissman, Haim,Rybtchinski, Boris,Kurth, Dirk G.. "The Kinetics of Growth of Metallo-supramolecular Polyelectrolytes in Solution". . p. 2898 - 2912. Retrieved 2017/10/06.