tris(4-fluorophenyl)bismuth dichloride

Base Information

• Chemical Name: tris(4-fluorophenyl)bismuth dichloride
• CAS No.: 118798-76-8
• Molecular Formula: C₁₈H₁₂BiCl₂F₃
• Molecular Weight: 565.175
• Mol file: 118798-76-8.mol

Synonyms:tris(4-fluorophenyl)bismuth dichloride

Chemical Property of tris(4-fluorophenyl)bismuth dichloride

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of tris(4-fluorophenyl)bismuth dichloride

There total 1 articles about tris(4-fluorophenyl)bismuth dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

tris(4-fluorophenyl)bismuthane (437-29-6) → tris(4-fluorophenyl)bismuth dichloride (118798-76-8)

Guidance literature:

With Cl₂; In chloroform; (Ar); through soln. of Bi compd. was bubbled Cl2 at - 10°C, excess of Cl2 was removed by Ar stream; solvent was removed in high vac. at - 5°C, residue was dissolved in CHCl3 and filtered over charcoal; recrystd. from EtOH/CHCl3 (4:1); elem. anal.;

Reference yield: 79.0%

cyclopent-2-enone (930-30-3) + tris(4-fluorophenyl)bismuth dichloride (118798-76-8) → 2-(4-Fluorophenyl)-2-cyclopenten-1-one (162011-76-9)

Guidance literature:

With tributylphosphine; N-ethyl-N,N-diisopropylamine; In dichloromethane; tert-butyl alcohol; at 25 ℃;

DOI:10.1021/ja048987i

Reference yield: 79.0%

1-benzyl-1,2,3,6-tetrahydropyridin-4-en-3-one (94923-25-8) + tris(4-fluorophenyl)bismuth dichloride (118798-76-8) → 1-benzyl-4-(4-fluoro-phenyl)-1,6-dihydro-2H-pyridin-3-one (916214-01-2)

Guidance literature:

With tributylphosphine; N-ethyl-N,N-diisopropylamine; In dichloromethane; tert-butyl alcohol; at 25 ℃; for 3h;

DOI:10.1016/j.tet.2006.05.092

upstream raw materials:

tris(4-fluorophenyl)bismuthane

Downstream raw materials:

(E)-2-(4-Fluoro-phenyl)-but-2-enal

(Z)-2-(4-Fluoro-phenyl)-but-2-enal

2-(4-Fluorophenyl)-2-cyclopenten-1-one

1-benzyl-4-(4-fluoro-phenyl)-1,6-dihydro-2H-pyridin-3-one

Refernces